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A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene

Abstract : A novel complex featuring a mesoionic carbene [Fe2(CO)5(trz)(μ-pdt)] (1) (trz = 1-phenyl-l,3-methyl,4-butyl-1,2,3-triazol-5-ylidene), was synthesized and spectroscopically and structurally characterized. The reduc-tive behaviour of this compound in the presence and in the absence of acid (CH3CO2H) was examined by cyclic voltammetry (CV) that revealed the lack of efficient activity towards proton reduction
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Contributor : Catherine Elleouet Connect in order to contact the contributor
Submitted on : Monday, July 20, 2020 - 3:10:47 PM
Last modification on : Friday, August 5, 2022 - 12:38:22 PM

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Andrea Mele, Simone Bertini, Martin Albrecht, Catherine Elleouet, François Pétillon, et al.. A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene. CHIMIA, 2020, 74 (6), pp.499-503. ⟨10.2533/chimia.2020.499⟩. ⟨hal-02902975⟩



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