Manganese Fluorene Phosphonates: Formation of Isolated Chains - Université de Bretagne Occidentale
Journal Articles Inorganics Year : 2018

Manganese Fluorene Phosphonates: Formation of Isolated Chains

Abstract

9,9-dimethylfluorenyl-2-phosphonic acid 1 was reacted with manganese nitrate tetrahydrate to produce under hydrothermal conditions the crystalline manganese phosphonate Mn(H2O)2[O2(OH)PC15H13]2·2H2O which crystallize in the P21/c space group. This compound is a rare example of Mn-phosphonate material featuring isolated chains. The interactions between these chains containing the 9,9-dimethylfluorenyl moieties, result from Van der Waals interactions involving the fluorene ligands and C···H–C hydrogen bonds as revealed by Hirshfeld Surfaces. This material features antiferromagnetic exchange interactions as revealed by the magnetic susceptibility as a function of the temperature.
Fichier principal
Vignette du fichier
inorganics-06-00092.pdf (3.7 Mo) Télécharger le fichier
Origin Publication funded by an institution

Dates and versions

hal-01870421 , version 1 (29-10-2021)

Licence

Identifiers

Cite

Clarisse Bloyet, Jean-Michel Rueff, Vincent Caignaert, Bernard Raveau, Jean-François Lohier, et al.. Manganese Fluorene Phosphonates: Formation of Isolated Chains. Inorganics, 2018, 6 (3), pp.92. ⟨10.3390/inorganics6030092⟩. ⟨hal-01870421⟩
131 View
70 Download

Altmetric

Share

More