Reaction of vinylacetylene with [Mo(.eta.5-C5H5)(CO)2]2. Reactivity of [{Mo(.eta.5-C5H5)(CO)2}(.mu.-HC.tplbond.CCH:CH2)]. Crystal structures of [{Mo(.eta.5-C5H5)(CO)2}2(.mu.-.eta.2,.eta.3-HC.tplbond.CCHCH3)][BF4] and of [[{Mo(.eta.5-C5H5)(CO)2}2]2-.mu.-(.mu.-HC.tplbond.CCH2CH2)2]

Nathalie Le Berre-Cosquer; Rene Kergoat; Paul l'Haridon

doi:10.1021/om00038a034

Reaction of vinylacetylene with [Mo(.eta.5-C5H5)(CO)2]2. Reactivity of [{Mo(.eta.5-C5H5)(CO)2}(.mu.-HC.tplbond.CCH:CH2)]. Crystal structures of [{Mo(.eta.5-C5H5)(CO)2}2(.mu.-.eta.2,.eta.3-HC.tplbond.CCHCH3)][BF4] and of [[{Mo(.eta.5-C5H5)(CO)2}2]2-.mu.-(.mu.-HC.tplbond.CCH2CH2)2]

Nathalie Le Berre-Cosquer ¹ Rene Kergoat ¹ Paul l'Haridon ²

1 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique

2 ISCR - Institut des Sciences Chimiques de Rennes

Document type :

Journal articles

Domain :

Chemical Sciences / Coordination chemistry

Chemical Sciences / Inorganic chemistry

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https://hal.univ-brest.fr/hal-01861326
Contributor : Nicolas Renard <>
Submitted on : Friday, August 24, 2018 - 12:13:22 PM
Last modification on : Thursday, March 5, 2020 - 2:07:40 PM

Reaction of vinylacetylene with [Mo(.eta.5-C5H5)(CO)2]2. Reactivity of [{Mo(.eta.5-C5H5)(CO)2}(.mu.-HC.tplbond.CCH:CH2)]. Crystal structures of [{Mo(.eta.5-C5H5)(CO)2}2(.mu.-.eta.2,.eta.3-HC.tplbond.CCHCH3)][BF4] and of [[{Mo(.eta.5-C5H5)(CO)2}2]2-.mu.-(.mu.-HC.tplbond.CCH2CH2)2]

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Reaction of vinylacetylene with [Mo(.eta.5-C5H5)(CO)2]2. Reactivity of [{Mo(.eta.5-C5H5)(CO)2}(.mu.-HC.tplbond.CCH:CH2)]. Crystal structures of [{Mo(.eta.5-C5H5)(CO)2}2(.mu.-.eta.2,.eta.3-HC.tplbond.CCHCH3)][BF4] and of [[{Mo(.eta.5-C5H5)(CO)2}2]2-.mu.-(.mu.-HC.tplbond.CCH2CH2)2]

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