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Reaction of vinylacetylene with [Mo(.eta.5-C5H5)(CO)2]2. Reactivity of [{Mo(.eta.5-C5H5)(CO)2}(.mu.-HC.tplbond.CCH:CH2)]. Crystal structures of [{Mo(.eta.5-C5H5)(CO)2}2(.mu.-.eta.2,.eta.3-HC.tplbond.CCHCH3)][BF4] and of [[{Mo(.eta.5-C5H5)(CO)2}2]2-.mu.-(.mu.-HC.tplbond.CCH2CH2)2]

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https://hal.univ-brest.fr/hal-01861326
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Submitted on : Friday, August 24, 2018 - 12:13:22 PM
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Nathalie Le Berre-Cosquer, Rene Kergoat, Paul l'Haridon. Reaction of vinylacetylene with [Mo(.eta.5-C5H5)(CO)2]2. Reactivity of [{Mo(.eta.5-C5H5)(CO)2}(.mu.-HC.tplbond.CCH:CH2)]. Crystal structures of [{Mo(.eta.5-C5H5)(CO)2}2(.mu.-.eta.2,.eta.3-HC.tplbond.CCHCH3)][BF4] and of [[{Mo(.eta.5-C5H5)(CO)2}2]2-.mu.-(.mu.-HC.tplbond.CCH2CH2)2]. Organometallics, American Chemical Society, 1992, 11 (2), pp.721 - 728. ⟨10.1021/om00038a034⟩. ⟨hal-01861326⟩

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