([CuII(tn)]2[FeII(CN)6])· KCl·5H2O (tn=1,3-diaminopropane): A two-dimensional bimetallic layered material with "Cu4Fe3" defective cubane units
Résumé
The new two-dimensional coordination compound ([CuII(tn)]2[-FeII(CN)6]) ·KCl·5H2O (1) (tn=1,3-diaminopropane), generated by six -Fe-CN-Cu- bridges, shows weak ferromagnetic interactions between the nearest Cu(II) ions through the diamagnetic [Fe(CN)6]4- anion.