Synthesis, characterization and electrochemical investigations of heterocyclic-selenocarboxylate iron complexes - Université de Bretagne Occidentale Access content directly
Journal Articles Inorganica Chimica Acta Year : 2016

Synthesis, characterization and electrochemical investigations of heterocyclic-selenocarboxylate iron complexes

Abstract

Selenocarboxylato complexes of iron containing heterocyclic group of the general formula CpFe(CO)2SeCO-het [het = 2-C4H3S (1), 2-C4H3O (2), -CH2-2-C4H3S (3)] were prepared from the reaction of iron selenide, (μ-Se)[FeCp(CO)2]2 and the corresponding heterocyclic acid chlorides. These complexes have been characterized by elemental analysis, UV-Vis, IR and 1H NMR spectroscopic techniques. The X-ray structure of 1 is determined and its electrochemical behavior has been described in details applying cyclic voltammetry. © 2016 Elsevier B.V.
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hal-01770460 , version 1 (19-04-2018)

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M. El-Khateeb, H. Abul-Futouh, H. Görls, W. Weigand, Laith.R Almazahreh. Synthesis, characterization and electrochemical investigations of heterocyclic-selenocarboxylate iron complexes. Inorganica Chimica Acta, 2016, 449, pp.14-19. ⟨10.1016/j.ica.2016.04.033⟩. ⟨hal-01770460⟩
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