Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: Structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H 2O)2](C(CN)3)4Cl2 (pn = 1,3-diaminopropane) - Université de Bretagne Occidentale
Journal Articles Chemical Communications Year : 2001

Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: Structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H 2O)2](C(CN)3)4Cl2 (pn = 1,3-diaminopropane)

Smail Triki
Chimie, Electrochimie Moléculaires et Chimie Analytique
Franck Thétiot
Chimie, Electrochimie Moléculaires et Chimie Analytique
J.S. Pala
  • Function : Author
S. Golhen
  • Function : Author
J.M. Clemente-Juan
  • Function : Author
C.J. Gómez-García
  • Function : Author
E. Coronado
  • Function : Author

Abstract

A new polynuclear copper(II) complex [Cu7(OH)6Cl2-(pn) 6(H2O)2](C(CN)3)4Cl 2 with hydroxo-bridging ligands has been prepared; the centrosymmetric cluster cation can be described as two Cu4O3Cl distorted cubane units sharing one copper cation.

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Chemical Sciences

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https://hal.univ-brest.fr/hal-01770139

Submitted on : Wednesday, April 18, 2018-4:15:58 PM

Last modification on : Tuesday, July 2, 2024-1:33:44 PM

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hal-01770139 , version 1 (18-04-2018)

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  • HAL Id : hal-01770139 , version 1

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Smail Triki, Franck Thétiot, J.S. Pala, S. Golhen, J.M. Clemente-Juan, et al.. Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: Structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H 2O)2](C(CN)3)4Cl2 (pn = 1,3-diaminopropane). Chemical Communications, 2001, 21, pp.2172-2173. ⟨hal-01770139⟩

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