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Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: Structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H 2O)2](C(CN)3)4Cl2 (pn = 1,3-diaminopropane)

Abstract : A new polynuclear copper(II) complex [Cu7(OH)6Cl2-(pn) 6(H2O)2](C(CN)3)4Cl 2 with hydroxo-bridging ligands has been prepared; the centrosymmetric cluster cation can be described as two Cu4O3Cl distorted cubane units sharing one copper cation.
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https://hal.univ-brest.fr/hal-01770139
Contributor : Nicolas Renard <>
Submitted on : Wednesday, April 18, 2018 - 4:15:58 PM
Last modification on : Wednesday, February 12, 2020 - 1:58:18 PM

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Smail Triki, Franck Thétiot, J.S. Pala, S. Golhen, J.M. Clemente-Juan, et al.. Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: Structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H 2O)2](C(CN)3)4Cl2 (pn = 1,3-diaminopropane). Chemical Communications, Royal Society of Chemistry, 2001, pp.2172-2173. ⟨hal-01770139⟩

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