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O-O bond cleavage by electrochemical reduction of a side-on peroxo dicopper model of hemocyanin.

Abstract : The redox properties of the μ-η2:η2 peroxo complex [Cu2(H6M4h)(O2)]2+ were elucidated. This study constitutes the first full electrochemical and spectroelectrochemical characterization of a side-on peroxo Cu2:O2 bioinorganic model complex. The peroxo complex is irreversibly reduced in a two- electron process localized on the peroxo ligand triggering the cleavage of the O-O bond
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https://hal.univ-brest.fr/hal-01769619
Contributor : Nicolas Renard <>
Submitted on : Wednesday, April 18, 2018 - 11:15:57 AM
Last modification on : Saturday, September 26, 2020 - 11:44:10 PM

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Isidoro López, Ana Gabriela Porras Gutiérrez, Bénédicte Douziech, Laurianne Wojcik, Yves Le Mest, et al.. O-O bond cleavage by electrochemical reduction of a side-on peroxo dicopper model of hemocyanin.. Chemical Communications, Royal Society of Chemistry, 2018, ⟨10.1039/C8CC01959B⟩. ⟨hal-01769619⟩

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