Supramolecular control of an organic radical coupled to a metal ion embedded at the entrance of a hydrophobic cavity - Université de Bretagne Occidentale Access content directly
Journal Articles Journal of the Chemical Society. Dalton Transactions Year : 2003

Supramolecular control of an organic radical coupled to a metal ion embedded at the entrance of a hydrophobic cavity

O. Sénèque
  • Function : Author
M. Campion
  • Function : Author
M. Giorgi
  • Function : Author
O. Reinaud
  • Function : Author

Abstract

A novel N3ArO-calix[6]arene-based system is presented. It allows the formation of an aryloxy radical bound to a metal ion (CuII or ZnII) that presents a free coordination site in a concave cavity. Its oxidative activity appears highly controlled by the supramolecular system hence providing a good model for radical enzymes such as Galactose oxidase. © 2003 The Royal Society of Chemistry.

Dates and versions

hal-01763903 , version 1 (11-04-2018)

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O. Sénèque, M. Campion, Bénédicte Douziech, M. Giorgi, Yves Le Mest, et al.. Supramolecular control of an organic radical coupled to a metal ion embedded at the entrance of a hydrophobic cavity. Journal of the Chemical Society. Dalton Transactions, 2003, 3 (22), pp.4216-4218. ⟨10.1039/b308255e⟩. ⟨hal-01763903⟩
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