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Journal articles
Supramolecular control of an organic radical coupled to a metal ion embedded at the entrance of a hydrophobic cavity
Abstract : A novel N3ArO-calix[6]arene-based system is presented. It allows the formation of an aryloxy radical bound to a metal ion (CuII or ZnII) that presents a free coordination site in a concave cavity. Its oxidative activity appears highly controlled by the supramolecular system hence providing a good model for radical enzymes such as Galactose oxidase. © 2003 The Royal Society of Chemistry.
https://hal.univ-brest.fr/hal-01763903
Contributor : Nicolas Renard <>
Submitted on : Wednesday, April 11, 2018 - 2:59:24 PM
Last modification on : Thursday, November 29, 2018 - 4:09:14 PM
Contributor : Nicolas Renard <>
Submitted on : Wednesday, April 11, 2018 - 2:59:24 PM
Last modification on : Thursday, November 29, 2018 - 4:09:14 PM
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