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Journal Articles Organometallics Year : 2005

N-heterocyclic carbene ligands as cyanide mimics in diiron models of the all-iron hydrogenase active site

Abstract

The reaction of [Fe2(μ-S(CH2)3S)(CO) 6] with an excess of 1,3-dimethylimidazol-2-ylidene (LMe) affords the mono- and disubstituted species [Fe2(μ-S(CH 2)3S)-(CO)5(LMe)] (1) and (Fe 2(μ-S(CH2)3(CO)4(L Me)2) respectively. The structures of 1 and 2 have been determined by X-ray crystallography. © 2005 American Chemical Society.

Dates and versions

hal-01763739 , version 1 (11-04-2018)

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Jean-François Capon, S.E. Hassnaoui, Frederic Gloaguen, Philippe P. Schollhammer, Jean Talarmin. N-heterocyclic carbene ligands as cyanide mimics in diiron models of the all-iron hydrogenase active site. Organometallics, 2005, 24 (9), pp.2020-2022. ⟨10.1021/om049132h⟩. ⟨hal-01763739⟩
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