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Synthesis and Characterization of an Isolable Base-Stabilized Silacycloprop-1-ylidene

Abstract : An isolable silacycloprop-1-ylidene stabilized by intramolecular complexation with an iminophosphorus ylide fragment was successfully synthesized and fully characterized. The formation of this small highly strained cyclic silylene involves an unprecedented SiIV→SiII rearrangement under very mild conditions.
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Ricardo Rodriguez, Thibault Troadec, Tsuyoshi Kato, Nathalie Saffon-Merceron, Jean-Marc Sotiropoulos, et al.. Synthesis and Characterization of an Isolable Base-Stabilized Silacycloprop-1-ylidene. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2012, 51 (29), pp.7158-7161. ⟨10.1002/anie.201201581⟩. ⟨hal-01646152⟩



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