Synthesis and Characterization of an Isolable Base-Stabilized Silacycloprop-1-ylidene

An isolable silacycloprop-1-ylidene stabilized by intramolecular complexation with an iminophosphorus ylide fragment was successfully synthesized and fully characterized. The formation of this small highly strained cyclic silylene involves an unprecedented SiIV→SiII rearrangement under very mild conditions.

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Chimie organique

Thibault Troadec : Connectez-vous pour contacter le contributeur

https://hal.univ-brest.fr/hal-01646152

Soumis le : lundi 4 décembre 2017-11:03:03

Dernière modification le : jeudi 11 avril 2024-13:08:11

Dates et versions

hal-01646152 , version 1 (04-12-2017)

Identifiants

HAL Id : hal-01646152 , version 1
DOI : 10.1002/anie.201201581

Citer

Ricardo Rodriguez, Thibault Troadec, Tsuyoshi Kato, Nathalie Saffon-Merceron, Jean-Marc Sotiropoulos, et al.. Synthesis and Characterization of an Isolable Base-Stabilized Silacycloprop-1-ylidene. Angewandte Chemie International Edition, 2012, 51 (29), pp.7158-7161. ⟨10.1002/anie.201201581⟩. ⟨hal-01646152⟩

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