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Journal articles
New side-bridged bismacrocycles and cross-bridged macrotricycles. Syntheses and Cu(ii) complexation study
Nicolas Bernier
1
Mustapha Allali
1
Raphaël Tripier
1
Françoise Conan
1
Véronique Patinec
1
Stéphanie Develay
1
Michel Le Baccon
1
Henri Handel
1
Nicolas Bernier 1
Mail :
Author
Mustapha Allali 1
Author
Raphaël Tripier 1
Mail :
Author IdHAL : raphael-tripier ORCID : https://orcid.org/0000-0001-9364-788X
Françoise Conan 1
Mail :
Author IdHAL : francoise-conan ORCID : https://orcid.org/0000-0002-0954-259X
Véronique Patinec 1
Mail :
Author IdHAL : veronique-patinec
Stéphanie Develay 1
Author
Michel Le Baccon 1
Author
Henri Handel 1
Author
1
CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique (6 Av Victor Le Gorgeu - BP 809 29285 BREST CEDEX - France)
- UBO - Université de Brest (Université de Bretagne Occidentale - 3 Rue des Archives 29238, Brest - France)
- INC - Institut de Chimie du CNRS (3 Rue Michel-Ange 75 016 Paris - France)
- CNRS - Centre National de la Recherche Scientifique : UMR6521 (France)
- IBSAM - Institut Brestois Santé Agro Matière (Université de Brest- UBO
29238 Brest - France)
- UBO - Université de Brest (Université de Bretagne Occidentale - 3 Rue des Archives 29238, Brest - France)
Abstract : Eight new cyclen based constrained macropolycycles (4a–4d, 5a–5d) have been obtained by reductive ring cleavage of polyaminal derivatives of bis-macrocycles or macrotricyclic polyammonium salts by sodium borohydride. The mononuclear and dinuclear Cu(II) complexes of these macropolycyclic ligands were isolated as solids and investigated by UV-Vis and EPR spectroscopies. The possibility to obtain the specific formation of mononuclear complexes constitutes an original feature of these new macropolycycles.
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Journal articles
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https://hal.univ-brest.fr/hal-01582163
Contributor : Nicolas Renard <>
Submitted on : Tuesday, September 5, 2017 - 4:25:12 PM
Last modification on : Thursday, November 29, 2018 - 4:09:19 PM
Contributor : Nicolas Renard <>
Submitted on : Tuesday, September 5, 2017 - 4:25:12 PM
Last modification on : Thursday, November 29, 2018 - 4:09:19 PM
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- HAL Id : hal-01582163, version 1
- DOI : 10.1039/B515150C
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UNIV-BREST | CNRS | CEMCA-BREST | INC-CNRS | IBSAM
Citation
Nicolas Bernier, Mustapha Allali, Raphaël Tripier, Françoise Conan, Véronique Patinec, et al.. New side-bridged bismacrocycles and cross-bridged macrotricycles. Syntheses and Cu(ii) complexation study. New Journal of Chemistry, Royal Society of Chemistry, 2006, 30 (3), ⟨10.1039/B515150C⟩. ⟨hal-01582163⟩
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