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Journal articles
Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site
Pierre-Yves Orain
1
Jean-François Capon
1
Nelly Kervarec
2
Frederic Gloaguen
1
François Y. Pétillon
1
Roger Pichon
2
Philippe Schollhammer
1
Jean Talarmin
1
Pierre-Yves Orain 1
Author
Jean-François Capon 1
Author
Nelly Kervarec 2
Author
Frederic Gloaguen 1
Author IdHAL : frederic-gloaguen ResearcherId : http://www.researcherid.com/rid/A-3570-2011 ORCID : https://orcid.org/0000-0003-0591-0196
François Y. Pétillon 1
Author IdHAL : francois-petillon
Roger Pichon 2
Author
Philippe P. Schollhammer 1
Author IdHAL : philippe-schollhammer ORCID : https://orcid.org/0000-0001-8161-7878
Jean Talarmin 1
Author
1
CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique (6 Av Victor Le Gorgeu - BP 809 29285 BREST CEDEX - France)
- UBO - Université de Brest (Université de Bretagne Occidentale - 3 Rue des Archives 29238, Brest - France)
- INC - Institut de Chimie du CNRS (3 Rue Michel-Ange 75 016 Paris - France)
- CNRS - Centre National de la Recherche Scientifique : UMR6521 (France)
- IBSAM - Institut Brestois Santé Agro Matière (Université de Brest- UBO
29238 Brest - France)
- UBO - Université de Brest (Université de Bretagne Occidentale - 3 Rue des Archives 29238, Brest - France)
2
RMN-RPE-SM - Plateforme technologique de Résonance Magnétique Nucléaire et de Résonance Paramagnétique Electronique (Université de Bretagne Occidentale, 6 Avenue le Gorgeu, CS93837 Brest Cedex 3, France - France)
- UBO - Université de Brest (Université de Bretagne Occidentale - 3 Rue des Archives 29238, Brest - France)
Abstract : Treatment of [Fe2(µ-pdt)(CO)6] (pdt = S(CH2)3S) with 1,10-phenanthroline (phen) in refluxing toluene affords the asymmetric complex [Fe2(µ-pdt)(CO)4(phen)] (1); the protonation of 1 with HBF4·OEt2 in CD2Cl2 at 203 K has been monitored by 1H NMR.
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Journal articles
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https://hal.univ-brest.fr/hal-01581437
Contributor : Nicolas Renard <>
Submitted on : Monday, September 4, 2017 - 4:24:03 PM
Last modification on : Thursday, October 3, 2019 - 8:50:07 AM
Contributor : Nicolas Renard <>
Submitted on : Monday, September 4, 2017 - 4:24:03 PM
Last modification on : Thursday, October 3, 2019 - 8:50:07 AM
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- HAL Id : hal-01581437, version 1
- DOI : 10.1039/B709287C
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UNIV-BREST | CEMCA-BREST | CNRS | INC-CNRS | IBSAM
Citation
Pierre-Yves Orain, Jean-François Capon, Nelly Kervarec, Frederic Gloaguen, François Y. Pétillon, et al.. Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site. Dalton Transactions, Royal Society of Chemistry, 2007, ⟨10.1039/B709287C⟩. ⟨hal-01581437⟩
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