Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site - Université de Bretagne Occidentale Access content directly
Journal Articles Dalton Transactions Year : 2007

Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site

Abstract

Treatment of [Fe2(µ-pdt)(CO)6] (pdt = S(CH2)3S) with 1,10-phenanthroline (phen) in refluxing toluene affords the asymmetric complex [Fe2(µ-pdt)(CO)4(phen)] (1); the protonation of 1 with HBF4·OEt2 in CD2Cl2 at 203 K has been monitored by 1H NMR.

Dates and versions

hal-01581437 , version 1 (04-09-2017)

Identifiers

Cite

Pierre-Yves Orain, Jean-François Capon, Nelly Kervarec, Frederic Gloaguen, François Y. Pétillon, et al.. Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site. Dalton Transactions, 2007, 34, ⟨10.1039/B709287C⟩. ⟨hal-01581437⟩
54 View
0 Download

Altmetric

Share

Gmail Facebook X LinkedIn More