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Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site

Pierre-Yves Orain 1 Jean-François Capon 1 Nelly Kervarec 2 Frederic Gloaguen 1 François Y. Pétillon 1 Roger Pichon 2 Philippe P. Schollhammer 1 Jean Talarmin 1 
1 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique
2 RMN-RPE-SM - Plateforme technologique de Résonance Magnétique Nucléaire et de Résonance Paramagnétique Electronique
Abstract : Treatment of [Fe2(µ-pdt)(CO)6] (pdt = S(CH2)3S) with 1,10-phenanthroline (phen) in refluxing toluene affords the asymmetric complex [Fe2(µ-pdt)(CO)4(phen)] (1); the protonation of 1 with HBF4·OEt2 in CD2Cl2 at 203 K has been monitored by 1H NMR.
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https://hal.univ-brest.fr/hal-01581437
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Submitted on : Monday, September 4, 2017 - 4:24:03 PM
Last modification on : Monday, October 11, 2021 - 2:23:46 PM

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Pierre-Yves Orain, Jean-François Capon, Nelly Kervarec, Frederic Gloaguen, François Y. Pétillon, et al.. Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe–Fe] hydrogenase active site. Dalton Transactions, 2007, 34, ⟨10.1039/B709287C⟩. ⟨hal-01581437⟩

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