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A Supramolecular Ladderlike Structure Formed by the Auto-Assembly of Benzene-1,3,5-triphosphonic Acid

Abstract : Benzene-1,3,5-triphosphonic acid 1, which is the phosphonic acid analogue of trimesic acid, forms a columnar packing in the solid state that is characterized by strong hydrogen bonds (contact distances O···O ranging from 2.55 to 2.60 Å) and π-stacking (d(Ar···Ar) = 3.89 and 3.69 Å) involving the aromatic rings, thus designing an organic supramolecular ladder structure by auto-assembly.
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https://hal.univ-brest.fr/hal-01581263
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Submitted on : Monday, September 4, 2017 - 2:51:43 PM
Last modification on : Thursday, July 2, 2020 - 3:21:25 AM

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Gary B. Hix, Vincent Caignaert, Jean-Michel Rueff, Loïc Le Pluart, John E. Warren, et al.. A Supramolecular Ladderlike Structure Formed by the Auto-Assembly of Benzene-1,3,5-triphosphonic Acid. Crystal Growth and Design, American Chemical Society, 2007, 7 (2), pp.208 - 211. ⟨10.1021/cg060813k⟩. ⟨hal-01581263⟩

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