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On the electrochemistry of diiron dithiolate complexes related to the active site of the [FeFe]H2ase

Abstract : A few recent electrochemical studies of diiron models of the iron-only hydrogenases' active site are summarized. Emphasis is put on the reduction mechanisms of hexacarbonyl complexes and on the different mechanisms of proton reduction that may operate depending on the nature of the complex and the strength of the acid. An attempt is made to discuss the thermodynamic and kinetic limitations of proton reduction processes supported by these compounds.
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https://hal.univ-brest.fr/hal-01580511
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Submitted on : Friday, September 1, 2017 - 4:09:00 PM
Last modification on : Thursday, October 3, 2019 - 8:50:07 AM

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Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe Schollhammer, Jean Talarmin. On the electrochemistry of diiron dithiolate complexes related to the active site of the [FeFe]H2ase. Comptes Rendus Chimie, Elsevier Masson, 2008, 11 (8), pp.842 - 851. ⟨10.1016/j.crci.2008.03.007⟩. ⟨hal-01580511⟩

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