On the electrochemistry of diiron dithiolate complexes related to the active site of the [FeFe]H2ase - Université de Bretagne Occidentale Access content directly
Journal Articles Comptes Rendus. Chimie Year : 2008

On the electrochemistry of diiron dithiolate complexes related to the active site of the [FeFe]H2ase

Abstract

A few recent electrochemical studies of diiron models of the iron-only hydrogenases' active site are summarized. Emphasis is put on the reduction mechanisms of hexacarbonyl complexes and on the different mechanisms of proton reduction that may operate depending on the nature of the complex and the strength of the acid. An attempt is made to discuss the thermodynamic and kinetic limitations of proton reduction processes supported by these compounds.

Dates and versions

hal-01580511 , version 1 (01-09-2017)

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Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin. On the electrochemistry of diiron dithiolate complexes related to the active site of the [FeFe]H2ase. Comptes Rendus. Chimie, 2008, 11 (8), pp.842 - 851. ⟨10.1016/j.crci.2008.03.007⟩. ⟨hal-01580511⟩
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