First insights into the protonation of dissymetrically disubstituted di-iron azadithiolate models of the [FeFe]H2ases active site - Université de Bretagne Occidentale Access content directly
Journal Articles Chemical Communications Year : 2008

First insights into the protonation of dissymetrically disubstituted di-iron azadithiolate models of the [FeFe]H2ases active site

Abstract

Dissymetrically disubstituted di-iron azadithiolate complexes [Fe2(CO)4(κ2-LL){μ-SCH2N(iPr)CH2S}] (LL = dppe, phen) protonate exclusively at the N atom of the bridge, like the hexacarbonyl precursor but in contrast to symmetrically disubstituted analogues; substitution of dppe for two CO groups noticeably increases the kinetics of the electrocatalytic proton reduction process.

Dates and versions

hal-01580431 , version 1 (01-09-2017)

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Salah Ezzaher, Pierre-Yves Orain, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, et al.. First insights into the protonation of dissymetrically disubstituted di-iron azadithiolate models of the [FeFe]H2ases active site. Chemical Communications, 2008, 22, ⟨10.1039/B801373J⟩. ⟨hal-01580431⟩
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