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Journal articles
Bismuth (III) coordination to cyclen and cyclam bearing four appended groups
Abstract : The synthesis of new cyclam and cyclen derivatives (respectively L1 and L2), able to efficiently coordinate to Bi(III) are presented here. The two ligands bearing two different pendant arms (two-pycolyl and two (2-(2-hydroxyethoxy)ethyl)-2-aminoacetamide in trans position) were synthesized in the aim to obtain stable and water soluble complexes. The thermodynamic and kinetic of the formation of the corresponding complexes in aqueous solution were studied by means of NMR and potentiometric investigations. The fast kinetic of complexation and the high stability of the complexes are encouraging for further application with the alpha-emitting 213Bi isotope.
https://hal.univ-brest.fr/hal-01580260
Contributor : Nicolas Renard <>
Submitted on : Friday, September 1, 2017 - 11:22:44 AM
Last modification on : Tuesday, May 14, 2019 - 9:04:01 AM
Contributor : Nicolas Renard <>
Submitted on : Friday, September 1, 2017 - 11:22:44 AM
Last modification on : Tuesday, May 14, 2019 - 9:04:01 AM