3,5-Diphosphonobenzoic Acid, a New Rigid Heterotrifunctional Building Block to Design Metal Organic Frameworks. Illustration with the Characterization of Cu 5 [(O 3 P) 2 -C 6 H 3 -CO 2 ] 2 (H 2 O) 6

Jean-Michel Rueff; Olivier Perez; Charles Simon; Christophe Lorilleux; Hélène Couthon; Paul-Alain Jaffres

doi:10.1021/cg900811k

3,5-Diphosphonobenzoic Acid, a New Rigid Heterotrifunctional Building Block to Design Metal Organic Frameworks. Illustration with the Characterization of Cu 5 [(O 3 P) 2 -C 6 H 3 -CO 2 ] 2 (H 2 O) 6

Jean-Michel Rueff ¹ Olivier Perez ¹ Charles Simon ¹ Christophe Lorilleux ² Hélène Couthon ² Paul-Alain Jaffres ²

1 CRISMAT - Laboratoire de cristallographie et sciences des matériaux

2 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique

Abstract : The synthesis of 1,3-diphophonobenzoic acid (H5L2), a rigid precursor belonging to the family of 1,3,5-trisubstituted benzene compounds, is reported following a straightforward two-step sequence. The new rigid hetero-trifunctional building block has been engaged with Cu(NO3)2·3H2O in hydrothermal synthesis to produce a new metal−organic framework (MOF) Cu5[L2]2(H2O)6 (3). The structure of compound 3 has been solved by X-ray diffraction on single crystal and can be described as inorganic columns running along the c axis and separated by the organic parts. Magnetic measurements have been performed in order to evaluate the magnetic behavior and the moments of the Cu2+ ions in this structure.

Type de document :

Article dans une revue

Crystal Growth and Design, American Chemical Society, 2009, 9 (10), pp.4262 - 4268. 〈10.1021/cg900811k〉

Domaine :

Chimie

Chimie / Chimie organique

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http://hal.univ-brest.fr/hal-01580253
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Soumis le : vendredi 1 septembre 2017 - 11:17:48
Dernière modification le : mercredi 4 juillet 2018 - 01:18:55

3,5-Diphosphonobenzoic Acid, a New Rigid Heterotrifunctional Building Block to Design Metal Organic Frameworks. Illustration with the Characterization of Cu 5 [(O 3 P) 2 -C 6 H 3 -CO 2 ] 2 (H 2 O) 6

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3,5-Diphosphonobenzoic Acid, a New Rigid Heterotrifunctional Building Block to Design Metal Organic Frameworks. Illustration with the Characterization of Cu 5 [(O 3 P) 2 -C 6 H 3 -CO 2 ] 2 (H 2 O) 6

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