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Synthesis of Phosphorus-Containing Chitosan Derivatives

Abstract : Three new phosphorus-containing chitosan derivatives were prepared in good yield under mild conditions from 6-O-triphenylmethyl-chitosan and native chitosan. The three reactions used are thioacylation by a phosphonodithioester, alkylation by a halogeno-phosphonate, and Michael addition using a tetraethyl vinylidenebisphosphonate. The modified chitosan derivatives were fully characterized; their solubilities and thermal properties were evaluated.
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https://hal.univ-brest.fr/hal-01580233
Contributor : Nicolas Renard <>
Submitted on : Friday, September 1, 2017 - 11:00:51 AM
Last modification on : Sunday, November 8, 2020 - 11:22:02 AM

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Fanny Lebouc, Isabelle Dez, Mihaela Gulea, Pierre-Jean Madec, Paul-Alain Jaffres. Synthesis of Phosphorus-Containing Chitosan Derivatives. Phosphorus, Sulfur, and Silicon and the Related Elements, Taylor & Francis, 2009, 184 (4), pp.872 - 889. ⟨10.1080/10426500802715585⟩. ⟨hal-01580233⟩

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