m-phosphonobenzoic acid and copper(II) as precursors of helical chain and lamellar hybrid materials - Université de Bretagne Occidentale Access content directly
Journal Articles CrystEngComm Year : 2009

m-phosphonobenzoic acid and copper(II) as precursors of helical chain and lamellar hybrid materials

Abstract

A 1D helical-chain material Cu6(H2O)7(m-PO3C6H4CO2)41, characterized by a non-centrosymmetric crystal structure, and a 2D lamellar hybrid material Cu(H2O)(m-PO3C6H4CO2H) 2 have been synthesised starting from m-phosphonobenzoic acid and copper(II). The pH of the reaction media regulates the formation of either 1 or 2.

Dates and versions

hal-01578094 , version 1 (28-08-2017)

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Jean-Michel Rueff, Vincent Caignaert, André Leclaire, Charles Simon, Jean-Pierre Haelters, et al.. m-phosphonobenzoic acid and copper(II) as precursors of helical chain and lamellar hybrid materials. CrystEngComm, 2009, 11 (4), ⟨10.1039/B816132C⟩. ⟨hal-01578094⟩
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