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m-phosphonobenzoic acid and copper(II) as precursors of helical chain and lamellar hybrid materials

Jean-Michel Rueff 1 Vincent Caignaert 1 André Leclaire 1 Charles Simon 1 Jean-Pierre Haelters 2 Paul-Alain Jaffres 2
1 CRISMAT - Laboratoire de cristallographie et sciences des matériaux
2 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique
Abstract : A 1D helical-chain material Cu6(H2O)7(m-PO3C6H4CO2)41, characterized by a non-centrosymmetric crystal structure, and a 2D lamellar hybrid material Cu(H2O)(m-PO3C6H4CO2H) 2 have been synthesised starting from m-phosphonobenzoic acid and copper(II). The pH of the reaction media regulates the formation of either 1 or 2.
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https://hal.univ-brest.fr/hal-01578094
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Submitted on : Monday, August 28, 2017 - 4:22:06 PM
Last modification on : Monday, December 13, 2021 - 1:04:02 PM

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Jean-Michel Rueff, Vincent Caignaert, André Leclaire, Charles Simon, Jean-Pierre Haelters, et al.. m-phosphonobenzoic acid and copper(II) as precursors of helical chain and lamellar hybrid materials. CrystEngComm, Royal Society of Chemistry, 2009, 11 (4), ⟨10.1039/B816132C⟩. ⟨hal-01578094⟩

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