An unexpected base-induced [1,4]-phospho-Fries rearrangement - Université de Bretagne Occidentale
Journal Articles Dalton Transactions Year : 2010

An unexpected base-induced [1,4]-phospho-Fries rearrangement

Abstract

An unexpected [1,4]-phospho-Fries rearrangement that gives rise to the formation of a O,O,O,O-tetraethyl methylenebis(thiophosphonate) derivative is reported. The regioselectivity of the metallation with n-BuLi or t-BuLi is the key factor that explains either the [1,4] or [1,3] rearrangement observed.

Dates and versions

hal-01577411 , version 1 (25-08-2017)

Identifiers

Cite

Mathieu Berchel, Jean-Yves Salaün, Hélène Couthon, Jean-Pierre Haelters, Paul-Alain Jaffres. An unexpected base-induced [1,4]-phospho-Fries rearrangement. Dalton Transactions, 2010, 39 (47), ⟨10.1039/C0DT00880J⟩. ⟨hal-01577411⟩
66 View
0 Download

Altmetric

Share

More