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Journal articles
An unexpected base-induced [1,4]-phospho-Fries rearrangement
Abstract : An unexpected [1,4]-phospho-Fries rearrangement that gives rise to the formation of a O,O,O,O-tetraethyl methylenebis(thiophosphonate) derivative is reported. The regioselectivity of the metallation with n-BuLi or t-BuLi is the key factor that explains either the [1,4] or [1,3] rearrangement observed.
https://hal.univ-brest.fr/hal-01577411
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Submitted on : Friday, August 25, 2017 - 3:40:28 PM
Last modification on : Wednesday, May 25, 2022 - 9:40:03 AM
Contributor : NICOLAS RENARD Connect in order to contact the contributor
Submitted on : Friday, August 25, 2017 - 3:40:28 PM
Last modification on : Wednesday, May 25, 2022 - 9:40:03 AM
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