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Journal Articles Dalton Transactions Year : 2010

An unexpected base-induced [1,4]-phospho-Fries rearrangement

Abstract

An unexpected [1,4]-phospho-Fries rearrangement that gives rise to the formation of a O,O,O,O-tetraethyl methylenebis(thiophosphonate) derivative is reported. The regioselectivity of the metallation with n-BuLi or t-BuLi is the key factor that explains either the [1,4] or [1,3] rearrangement observed.

Dates and versions

hal-01577411 , version 1 (25-08-2017)

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Mathieu Berchel, Jean-Yves Salaün, Hélène Couthon, Jean-Pierre Haelters, Paul-Alain Jaffres. An unexpected base-induced [1,4]-phospho-Fries rearrangement. Dalton Transactions, 2010, 39 (47), ⟨10.1039/C0DT00880J⟩. ⟨hal-01577411⟩
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