Self-induced "electroclick" immobilization of a copper complex onto self-assembled monolayers on a gold electrode - Université de Bretagne Occidentale Access content directly
Journal Articles Dalton Transactions Year : 2010

Self-induced "electroclick" immobilization of a copper complex onto self-assembled monolayers on a gold electrode

Abstract

We report the self-induced "electroclick" immobilization of the [Cu(II)(6-ethynyl-TMPA)(H(2)O)](2+) complex, by its simple electro-reduction, onto a mixed azidoundodecane-/decane-thiol modified gold electrode. The redox response of the grafted [Cu(II/I)(TMPA)] at the modified electrode is fully reversible indicating no Cu coordination change and a fast electron transfer.

Dates and versions

hal-01175772 , version 1 (12-07-2015)

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Antoine Gomila, Nicolas Le Poul, Nathalie Cosquer, Jean-Michel Kerbaol, Jean-Marc Noël, et al.. Self-induced "electroclick" immobilization of a copper complex onto self-assembled monolayers on a gold electrode. Dalton Transactions, 2010, 39 (48), pp.11516--11518. ⟨10.1039/c0dt01093f⟩. ⟨hal-01175772⟩
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