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[FeFe] Hydrogenase Models: an Overview

Abstract : This chapter focuses on models for the mixed‐valent Hox state as well as protonation reactions of Hred models and on some significant insights into proton reduction chemistry. Although numerous [FeFe] hydrogenase model complexes exist, synthetic access to iron‐chalcogenolato compounds is limited to substitution reactions and oxidative additions. During the past two decades, significant development in modeling the active site of [FeFe] hydrogenases allowed to reveal the fundamental modes of action at the molecular level.
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Ulf-Peter Apfel, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin, Wolfgang Weigand. [FeFe] Hydrogenase Models: an Overview. Bioinspired Catalysis, Metal-Sulfur Complexes., chapitre 4, Wiley‐VCH, pp.79-104, 2015, Part II : Model Complexes of the Active Site of Hydrogenases-Proton and Dihydrogen Activation, 9783527333080. ⟨10.1002/9783527664160.ch4⟩. ⟨hal-02127128⟩



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