Electrochemical generation of substrate-binding sites in organometallic complexes with the {Mo2(µ-SR)n} core. Electrosynthesis of cyanide and isocyanide derivatives

The electrochemical activation of dinuclear molybdenum thiolate complexes and the reactivity of electrogenerated intermediates toward CO, RNC and RCN are described.

Keywords

Cyclic Voltammetry Reductive Cleavage Chimie Analytique Radical Cation Intermediate Isocyanide Ligand

Domains

Chemical Sciences

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https://hal.univ-brest.fr/hal-02127056

Submitted on : Monday, May 13, 2019-10:50:07 AM

Last modification on : Thursday, November 30, 2023-3:36:28 AM

Dates and versions

hal-02127056 , version 1 (13-05-2019)

Identifiers

HAL Id : hal-02127056 , version 1
DOI : 10.1007/978-94-011-1628-2_3

Cite

Frederic Gloaguen, C. Le Floc’h, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin, et al.. Electrochemical generation of substrate-binding sites in organometallic complexes with the {Mo2(µ-SR)n} core. Electrosynthesis of cyanide and isocyanide derivatives. Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds, springer, pp.33-38, 1993, NATO ASI Series, ⟨10.1007/978-94-011-1628-2_3⟩. ⟨hal-02127056⟩

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