Electrochemical generation of substrate-binding sites in organometallic complexes with the {Mo2(µ-SR)n} core. Electrosynthesis of cyanide and isocyanide derivatives

The electrochemical activation of dinuclear molybdenum thiolate complexes and the reactivity of electrogenerated intermediates toward CO, RNC and RCN are described.

Mots clés

Cyclic Voltammetry Reductive Cleavage Chimie Analytique Radical Cation Intermediate Isocyanide Ligand

Domaines

Chimie

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https://hal.univ-brest.fr/hal-02127056

Soumis le : lundi 13 mai 2019-10:50:07

Dernière modification le : jeudi 11 avril 2024-13:08:12

Dates et versions

hal-02127056 , version 1 (13-05-2019)

Identifiants

HAL Id : hal-02127056 , version 1
DOI : 10.1007/978-94-011-1628-2_3

Citer

Frederic Gloaguen, C. Le Floc’h, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin, et al.. Electrochemical generation of substrate-binding sites in organometallic complexes with the {Mo2(µ-SR)n} core. Electrosynthesis of cyanide and isocyanide derivatives. Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds, springer, pp.33-38, 1993, NATO ASI Series, ⟨10.1007/978-94-011-1628-2_3⟩. ⟨hal-02127056⟩

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