Electrochemical generation of substrate-binding sites in organometallic complexes with the {Mo2(µ-SR)n} core. Electrosynthesis of cyanide and isocyanide derivatives

Abstract : The electrochemical activation of dinuclear molybdenum thiolate complexes and the reactivity of electrogenerated intermediates toward CO, RNC and RCN are described.
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Submitted on : Monday, May 13, 2019 - 10:50:07 AM
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Frederic Gloaguen, C. Le Floc’h, François Y. Pétillon, Philippe Schollhammer, Jean Talarmin, et al.. Electrochemical generation of substrate-binding sites in organometallic complexes with the {Mo2(µ-SR)n} core. Electrosynthesis of cyanide and isocyanide derivatives. Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds, springer, pp.33-38, 1993, NATO ASI Series, ⟨10.1007/978-94-011-1628-2_3⟩. ⟨https://link.springer.com/chapter/10.1007/978-94-011-1628-2_3⟩. ⟨hal-02127056⟩

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