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Electrochemical generation of substrate-binding sites in organometallic complexes with the {Mo2(µ-SR)n} core. Electrosynthesis of cyanide and isocyanide derivatives

Frederic Gloaguen 1 C. Le Floc’h 1 François Y. Pétillon 1 Philippe P. Schollhammer 1 Jean Talarmin 1 M. El Khalifa 2 Jean-Yves Saillard 2 
1 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique
2 ISCR - Institut des Sciences Chimiques de Rennes
Abstract : The electrochemical activation of dinuclear molybdenum thiolate complexes and the reactivity of electrogenerated intermediates toward CO, RNC and RCN are described.
Keywords : Cyclic Voltammetry Reductive Cleavage Chimie Analytique Radical Cation Intermediate Isocyanide Ligand
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https://hal.univ-brest.fr/hal-02127056
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Submitted on : Monday, May 13, 2019 - 10:50:07 AM
Last modification on : Friday, December 10, 2021 - 3:52:15 PM

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UNIV-BREST | UNIV-RENNES1 | CNRS | INSA-RENNES | ISCR | ISCR-CTI | INC-CNRS | UR1-UFR-SPM | CEMCA-BREST | UNIV-RENNES | INSA-GROUPE | IBSAM | UR1-MMS

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Frederic Gloaguen, C. Le Floc’h, François Y. Pétillon, Philippe P. Schollhammer, Jean Talarmin, et al.. Electrochemical generation of substrate-binding sites in organometallic complexes with the {Mo2(µ-SR)n} core. Electrosynthesis of cyanide and isocyanide derivatives. Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds, springer, pp.33-38, 1993, NATO ASI Series, ⟨10.1007/978-94-011-1628-2_3⟩. ⟨hal-02127056⟩

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