, Spin-Crossover Materials, Properties and Applications, 2013.

P. Gütlich and . Goodwin, Top. Curr. Chem, pp.233-235, 2004.

N. Pittala, F. Thétiot, S. Triki, K. Boukheddaden, G. Chastanet et al., Cooperative 1D Triazole-Based Spin Crossover Fe II Material With Exceptional Mechanical Resilience, Chem. Mater, vol.29, pp.490-494, 2017.

H. Phan, J. J. Hrudka, D. Igimbayeva, L. M. Lawson-daku, and M. Shatruk, A simple approach for predicting the spin state of homoleptic Fe(II) tris-diimine complexes, J. Am. Chem. Soc, vol.139, pp.6437-6447, 2017.

N. Pittala, T. Thétiot, C. Charles, S. Triki, K. Boukheddaden et al., An unprecedented trinuclear Fe II triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature, Chem. Commun, vol.53, pp.8356-8359, 2017.

E. Milin, V. Patinec, S. Triki, E. Bendeif, S. Pillet et al., Elastic Frustration Triggering Photoinduced Hidden Hysteresis and Multistability in a Two-Dimensional Photoswitchable Hofmann-Like Spin-Crossover Metal-Organic Framework, Inorg. Chem, vol.55, pp.11652-11661, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01407977

M. Shatruk, H. Phan, B. A. Chrisostomo, and A. Suleimenova, Symmetry-breaking structural phase transitions in spin crossover complexes, Coord. Chem. Rev, pp.62-73, 2015.

C. Atmani, F. El-hajj, S. Benmansour, M. Marchivie, S. Triki et al., Guidelines to design new spin crossover materials, Coord. Chem. Rev, vol.254, pp.1559-1569, 2010.
URL : https://hal.archives-ouvertes.fr/hal-01577333

E. Coronado, J. R. Galán-mascarós, M. Monrabal-capilla, J. García-martínez, and P. Pardo-ibáñez, Bistable Spin-Crossover Nanoparticles Showing Magnetic Thermal Hysteresis near Room Temperature, Adv. Mater, vol.19, pp.1359-1361, 2007.

V. Shalabaeva, K. Ridier, S. Rat, M. D. Manrique-juarez, L. Salmon et al., Room temperature current modulation in large area electronic junctions of spin crossover thin films, Appl. Phys. Lett, p.13301, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01961778

K. Senthil-kumar and M. Ruben, Emerging trends in spin crossover (SCO) based functional materials and devices, Coord. Chem. Rev, vol.346, pp.176-205, 2017.

J. Dugay, M. Giménez-marqués, T. Kozlova, H. W. Zandbergen, E. Coronado et al., Spin switching in electronic devices based on 2D assemblies of spin-crossover nanoparticles, Adv.Mater, vol.27, pp.1288-1293, 2015.

I. Jeon, J. G. Park, C. R. Haney, and T. D. Harris, Spin crossover iron(II) complexes as PARACEST MRI thermometers, Chem. Sci, vol.5, pp.2461-2465, 2014.

N. Baadji and S. Sanvito, Phys. Rev. Lett, vol.108, p.217201, 2012.

F. Prins, M. ;-monrabal-capilla, E. A. Osorio, E. Coronado, and H. S. Van-der-zant, Room-temperature electrical addressing of a bistable spin-crossover molecular system, Adv. Mater, vol.23, pp.1545-1549, 2011.

A. Bousseksou, N. Negre, M. Goiran, L. Salmon, J. P. Tuchagues et al., Dynamic triggering of a spin-transition by a pulsed magnetic field, Eur. Phys. J. B, vol.13, pp.451-456, 2000.

A. Bousseksou, G. Molnár, L. Salmon, and W. Nicolazzi, Molecular spin crossover phenomenon: recent achievements and prospects, Chem. Soc. Rev, vol.40, pp.3313-3335, 2011.

P. Gütlich and H. A. Goodwin, Spin Crossover in Transition Metal Compounds I-III, vol.233, p.235, 2004.

J. Linares, E. Codjovi, Y. Garcia, P. Gutlich, A. B. Gaspar et al., Pressure and temperature spin crossover sensors with optical detection, Beilstein J. Org. Chem, vol.2012, issue.4, pp.342-391, 2013.

C. Jureschi, J. Linares, A. Boulmaali, P. R. Dahoo, A. Rotaru et al., Pressure and Temperature Sensors Using Two Spin Crossover Materials, Sensors, vol.16, p.187, 2016.
URL : https://hal.archives-ouvertes.fr/insu-01262735

D. Boinnard, A. Bousseksou, A. Dworkin, J. Savariault, F. Varret et al., Two-step spin conversion of [Fe II (5-NO 2-sal-N(1,4,7,10))]: 292, 153, and 103 K X-ray crystal and molecular structure, infrared, magnetic, Mössbauer, calorimetric, and theoretical studies, Inorg. Chem, vol.33, issue.23, pp.11563-11572, 1994.

W. Bauer, S. Schlamp, and B. Weber, A ladder type iron(II) coordination polymer with cooperative spin transition, Chem. Commun, vol.48, pp.10222-10224, 2012.

B. Weber, E. S. Kaps, J. Obel, K. Achterhold, and F. G. Parak, Synthesis and Characterization of a Dinuclear Iron(II) Spin Crossover Complex with Wide Hysteresis, Inorg. Chem, vol.47, pp.10779-10787, 2008.

B. Weber, E. Kaps, J. Weigand, C. Carbonera, J. Le?tard et al., Cooperative Iron(II) Spin Crossover Complexes with N 4 O 2 Coordination Sphere, Inorg. Chem, vol.47, pp.487-496, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00258997

B. Weber, C. Carbonera, C. Desplanches, and J. Létard, Stepwise Spin Transition in a Mononuclear Iron(II) Complex with Unusually Wide Plateau, Eur. J. Inorg. Chem, vol.10, pp.1589-1598, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00295165

B. Weber, E. S. Kaps, C. Desplanches, J. Létard, K. Achterhold et al., Synthesis and Characterisation of two new Iron(II) Spin-Crossover Complexes with N 4 O 2 Coordination spheres-Optimizing Preconditions for Cooperative Interactions, Eur. J. Inorg. Chem, pp.4891-4898, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00332990

B. Weber, W. Bauer, J. Obel, O. Iasco, E. Rivière et al., Fe II (pap-5NO 2 ) 2 and Fe II (qsal-5NO 2 ) 2 Schiff-Base Spin-Crossover Complexes: A Rare Example with Photomagnetism and RoomTemperature Bistability, Angew. Chem., Int. Ed, vol.47, issue.30, pp.1791-1799, 2008.

L. Zhang, G. Xu, H. Xu, V. Mereacre, Z. Wang et al., Synthesis, magnetic and photomagnetic study of new iron(II) spin-crossover complexes with N 4 O 2 coordination sphere, Dalton Trans, vol.39, pp.4856-4868, 2010.

T. Kuroda-sowa, Z. Senzaki, Y. Yu, K. Sugimoto, M. Maekawa et al., Abrupt Spin Transitions and LIESST Effects Observed in Fe II Spin-crossover Complexes with Extended ?-Conjugated Schiffbase Ligands Having N 4 O 2 Donor Sets, Chem. Lett, vol.37, issue.33, pp.6711-6714, 1216.

H. Wang, C. Desplanches, P. Dagault, and J. Letard, A new family of diamagnetic macrocyclic Fe(II) compounds exhibiting the LIESST effect at high temperatures, Dalton Trans, vol.43, pp.15346-15350, 2014.
URL : https://hal.archives-ouvertes.fr/hal-01074580

J. S. Costa, C. Balde, C. Carbonera, D. Denux, A. Wattiaux et al., Photomagnetic Properties of an Iron(II) LowSpin Complex with an Unusually Long-Lived Metastable LIESST State, Inorg. Chem, vol.46, pp.4114-4119, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00149072

J. S. Costa, P. Guionneau, and J. Létard, Photomagnetic properties of the [Fe(L 222 (N 3 O 2 ))(CN) 2 ]?H 2 O complex: a fascinating example of multimetastability, J. Phys.: Conf. Series, vol.21, pp.67-72, 2005.

S. M. Nelson, P. D. Mcllroy, and C. S. Stevenson, Quadridentate versus Quinquedentate Co-ordination of some N, and N,O, Macrocyclic Ligands and an Unusual Thermally controlled Quintet?Singlet Spin Transition in an Iron(II) Complex, J. Chem. Soc, pp.991-995, 1986.

C. Holzhacker, M. J. Calhorda, A. Gil, M. D. Carvalho, L. P. Ferreira et al., Six-coordinate high-spin iron(II) complexes with bidentate PN ligands based on 2-aminopyridine-new Fe(II) spin crossover systems, Dalton Trans, vol.43, pp.11152-11164, 2014.

E. König, G. Ritter, H. A. Goodwin, and I. Br, 57 Fe Mössbauer effect study of a presumed singlet-triplet, Chem. Phys. Lett, vol.31, pp.543-546, 1975.

P. Rosa, A. Debay, L. Capes, G. Chastanet, A. Bousseksou et al., Eur. J. Inorg. Chem, pp.3017-3019, 2004.

S. Yergeshbayeva, J. J. Hrudka, J. Lengyel, R. Erkasov, S. A. Stoian et al., Heteroleptic Fe(II) Complexes with N 4 S 2 Coordination as a Platform for Designing Spin-Crossover Materials, Inorg. Chem, vol.56, pp.11096-11103, 2017.

A. Arroyave, A. Lennartson, A. Dragulescu-andrasi, K. S. Pedersen, S. Piligkos et al., Spin Crossover in Fe(II) Complexes with N 4 S 2 Coordination, Inorg. Chem, vol.55, pp.5904-5913, 2016.

R. W. Hogue,

R. G. Miller and S. Brooker, Spin Crossover in Dinuclear N 4 S 2 Iron(II) Thioether-Triazole Complexes: Access to, States. Inorg. Chem, vol.55, pp.4152-4165, 2016.

A. Lennartson, A. D. Bond, S. Piligkos, and C. J. Mckenzie, Four-Site Cooperative Spin Crossover in a Mononuclear Fe II Complex, Angew. Chem. Int. Ed, vol.51, pp.11049-11052, 2012.

M. Yamasaki and T. Ishida, First Iron(II) Spin-crossover Complex with an N 5 S Coordination Sphere, Chem. Lett, vol.44, pp.920-921, 2015.

C. D. Mekuimemba, F. Conan, A. J. Mota, M. A. Palacios, E. Colacio et al., On the Magnetic Coupling and Spin Crossover Behavior in Complexes Containing the Head-to-Tail [Fe II 2 (?-SCN) 2 ] Bridging Unit: A Magnetostructural Experimental and Theoretical Study, Inorg. Chem, vol.57, pp.2184-2192, 2018.

K. Pohl, K. Wieghardt, B. Nuber, and J. Weiss, Preparation and Magnetism of the Binuclear Iron(II) Complexes [{Fe(C 9 H 21 N 3 )X 2 } 2 ] (X = NCS, NCO, or N) and their Reaction with NO. Crystal Structures of

, J. Chem. Soc, pp.187-192, 1987.

A. A. Salaudeen, C. A. Kilner, and M. A. Halcrow, Mononuclear and dinuclear iron thiocyanate and selenocyanate complexes of tris-pyrazolylmethane ligands, Polyhedron, vol.27, pp.2569-2576, 2008.

A. C. Mcquilken, Y. Jiang, M. A. Siegler, and D. P. Goldberg, Addition of dioxygen to an N 4 S(thiolate) iron(II) cysteine dioxygenase model gives a structurally characterized sulfinato-iron(II) complex, J. Am. Chem. Soc, vol.134, pp.8758-8761, 2012.

R. T. Jonas, M. Stack, and T. D. , Synthesis and Characterization of a Family of Systematically Varied Tris(2-pyridyl)methoxymethane Ligands: Copper(I) and Copper(II) Complexes, Inorg. Chem, vol.37, pp.6615-6629, 1998.

P. Guionneau, M. Marchivie, G. Bravic, J. Létard, and D. Chasseau, Top. Curr. Chem, p.97, 2004.

M. Kabesova, J. Gazo, and O. Kahn, Structure and classification of thiocyanates and the mutual influence of their ligands, Molecular Magnetism, vol.34, pp.53-86, 1980.

E. Milin, B. Benaicha, F. El-hajj, V. Patinec, S. Triki et al., Magnetic Bistability in Macrocycle-Based Fe II SpinCrossover Complexes: Counter Ion and Solvent Effects, Eur. J. Inorg. Chem, pp.5305-5314, 2016.

J. Tao, J. Wei, R. Huang, R. Zheng, and L. , Polymorphism in spin-crossover systems, Chem. Soc. Rev, vol.41, pp.703-737, 2012.

R. Wei, B. Li, J. Tao, R. Huang, L. Zheng et al., Making SpinCrossover Crystals by Successive Polymorphic Transformations, Inorg. Chem, vol.50, pp.1170-1172, 2011.

B. Li, R. Wei, J. Tao, R. Huang, L. Zheng et al., Solvent-Induced Transformation of Single Crystals of a Spin-Crossover (SCO) Compound to Single Crystals with Two Distinct SCO Centers, J. Am. Chem. Soc, vol.132, pp.1558-1566, 2010.

V. Smeets, M. Wolff, J. A. Wolny, V. Schünemann, M. M. Dîrtu et al., Spin State Crossover, Vibrational, Computational, and Structural Studies of Fe II 1-Isopropyl-1H-tetrazole Derivatives, Eur. J. Inorg. Chem, pp.394-413, 2018.

, HyperChem 5, 1997.

, Xcalibur CCD/RED CrysAlis Software system. Oxford Diffraction Ltd, 2006.

A. Altomare, M. C. Burla, M. Camalli, C. Cascarano, C. Giacovazzo et al., SIR97: a new tool for crystal structure determination and refinement, J. Appl. Cryst, vol.32, issue.62, pp.3-8, 1999.

, For Table of Contents Only TOC synopsis

, One-dimensional Thiocyanato-Bridged Fe(II) Spin Crossover Cooperative Polymer With Unusual FeN 5 S Coordination Sphere

K. Nebbali, C. Donacier-mekuimemba, C. Charles, G. Chastanet, A. J. Mota et al., A new cooperative Fe(II) spin crossover (SCO) coordination polymer, with a single end-to-end thiocyanato bridges and an unusual FeN 5 S coordination sphere