A μ-η1-azavinylidene complex: Intramolecular condensation of two acetonitrile ligands at a dinuclear molybdenum(III) site - Université de Bretagne Occidentale Access content directly
Journal Articles European Journal of Inorganic Chemistry Year : 1999

A μ-η1-azavinylidene complex: Intramolecular condensation of two acetonitrile ligands at a dinuclear molybdenum(III) site

Abstract

Removal of a proton from one of the two coordinated acetonitrile ligands in [Mo2Cp2(μ-SMe)3(CH3CN)2](BF4) (1) initiates its intramolecular condensation with the second of the acetonitrile ligands attached to the bimetallic [Mo2Cp2(μ-SMe)3] core, thereby giving rise to the novel μ- η1-azavinylidene complex (Mo2Cp2(μ-SMe)3[μ-η1-N=C(CH3)-CH2CN]) (2). Complex 2 has been characterized by NMR and X-ray methods.
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Dates and versions

hal-01771449 , version 1 (19-04-2018)

Identifiers

  • HAL Id : hal-01771449 , version 1

Cite

Philippe P. Schollhammer, M. Pichon, K.W. Muir, François Pétillon, R. Pichon, et al.. A μ-η1-azavinylidene complex: Intramolecular condensation of two acetonitrile ligands at a dinuclear molybdenum(III) site. European Journal of Inorganic Chemistry, 1999, pp.221--223. ⟨hal-01771449⟩
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