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Journal articles
A μ-η1-azavinylidene complex: Intramolecular condensation of two acetonitrile ligands at a dinuclear molybdenum(III) site
Abstract : Removal of a proton from one of the two coordinated acetonitrile ligands in [Mo2Cp2(μ-SMe)3(CH3CN)2](BF4) (1) initiates its intramolecular condensation with the second of the acetonitrile ligands attached to the bimetallic [Mo2Cp2(μ-SMe)3] core, thereby giving rise to the novel μ- η1-azavinylidene complex (Mo2Cp2(μ-SMe)3[μ-η1-N=C(CH3)-CH2CN]) (2). Complex 2 has been characterized by NMR and X-ray methods.
https://hal.univ-brest.fr/hal-01771449
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Submitted on : Thursday, April 19, 2018 - 2:59:10 PM
Last modification on : Monday, October 11, 2021 - 2:22:08 PM
Contributor : NICOLAS RENARD Connect in order to contact the contributor
Submitted on : Thursday, April 19, 2018 - 2:59:10 PM
Last modification on : Monday, October 11, 2021 - 2:22:08 PM