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Journal Articles Synthetic Metals Year : 1999

Molecular hybrids combining magnetic complexes and organic π-donors

F. Bérézovsky
  • Function : Author
J.S. Pala
  • Function : Author
Agathe Riou
  • Function : Author
P. Molinié
  • Function : Author

Abstract

Combination of the magnetic dinuclear chromium(III) anion [Cr2(C2O4)(NCS)8]4 with the organic ET π-donor (ET = BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene) yields two novel molecular hybrids (ET)n[Cr2(C2O4)(NCS)8] (1:n = 5; 2:n = 8). The particular arrangement of the organic units in the former leads to an unprecedented two-dimensional organic sublattice nearly similar to that observed in κ-phase structures. The packing of the ET units in 2 is near that observed in β-phase.

Dates and versions

hal-01771394 , version 1 (19-04-2018)

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Smail Triki, F. Bérézovsky, J.S. Pala, Agathe Riou, P. Molinié. Molecular hybrids combining magnetic complexes and organic π-donors. Synthetic Metals, 1999, 103, pp.1974--1975. ⟨10.1016/S0379-6779(98)00902-3⟩. ⟨hal-01771394⟩
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