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Molecular hybrids combining magnetic complexes and organic π-donors

Abstract : Combination of the magnetic dinuclear chromium(III) anion [Cr2(C2O4)(NCS)8]4 with the organic ET π-donor (ET = BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene) yields two novel molecular hybrids (ET)n[Cr2(C2O4)(NCS)8] (1:n = 5; 2:n = 8). The particular arrangement of the organic units in the former leads to an unprecedented two-dimensional organic sublattice nearly similar to that observed in κ-phase structures. The packing of the ET units in 2 is near that observed in β-phase.
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https://hal.univ-brest.fr/hal-01771394
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Submitted on : Thursday, April 19, 2018 - 2:49:31 PM
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Smail Triki, F. Bérézovsky, J.S. Pala, A. Riou, P. MoliniÉ. Molecular hybrids combining magnetic complexes and organic π-donors. Synthetic Metals, Elsevier, 1999, 103, pp.1974--1975. ⟨10.1016/S0379-6779(98)00902-3⟩. ⟨hal-01771394⟩

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