μ-alkylidyne and μ-alkylidene complexes from a bridging side-on vinylidene sulfur-rich dimolybdenum precursor - Université de Bretagne Occidentale Access content directly
Journal Articles Organometallics Year : 2002

μ-alkylidyne and μ-alkylidene complexes from a bridging side-on vinylidene sulfur-rich dimolybdenum precursor

N. Cabon
P. Schollhammer
  • Function : Author
K.W. Muir
  • Function : Author

Abstract

The reaction of the μ-vinylidene sulfur-rich dimolybdenum complexes with μ-alkyldyne derivatives was investigated. The reaction resulted in good yield, and when treated with a HBF4·Et2O based complex it readily converted into μ-alkyldene species. The α-agostic interactions in the μ-alkyldene complexes were revealed through NMR spectroscopy.

Dates and versions

hal-01771319 , version 1 (19-04-2018)

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N. Cabon, P. Schollhammer, François Pétillon, J. Talarmin, K.W. Muir. μ-alkylidyne and μ-alkylidene complexes from a bridging side-on vinylidene sulfur-rich dimolybdenum precursor. Organometallics, 2002, 21, pp.448--450. ⟨10.1021/om010853f⟩. ⟨hal-01771319⟩
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