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μ-alkylidyne and μ-alkylidene complexes from a bridging side-on vinylidene sulfur-rich dimolybdenum precursor

Abstract : The reaction of the μ-vinylidene sulfur-rich dimolybdenum complexes with μ-alkyldyne derivatives was investigated. The reaction resulted in good yield, and when treated with a HBF4·Et2O based complex it readily converted into μ-alkyldene species. The α-agostic interactions in the μ-alkyldene complexes were revealed through NMR spectroscopy.
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https://hal.univ-brest.fr/hal-01771319
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Submitted on : Thursday, April 19, 2018 - 2:47:14 PM
Last modification on : Thursday, October 3, 2019 - 8:50:02 AM

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N. Cabon, P. Schollhammer, François Pétillon, J. Talarmin, K.W. Muir. μ-alkylidyne and μ-alkylidene complexes from a bridging side-on vinylidene sulfur-rich dimolybdenum precursor. Organometallics, 2002, 21, pp.448--450. ⟨10.1021/om010853f⟩. ⟨hal-01771319⟩

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