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Dinuclear molybdenum thiolato-bridged compounds: Syntheses, reactivities and electrochemical studies of site-substrate interactions

François Pétillon 1 Philippe Schollhammer 1 J. Talarmin 1 K.W. Muir
1 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique
Abstract : The synthesis, reactivity, structures and electrochemistry of dimolybdenum complexes jointly stabilized by cyclopentadienyl and bridging thiolate ligands are reviewed. The complexes involved are principally those of molybdenum(II) and molybdenum(III) and they contain from one to four thiolate bridges. It is shown that their reactivity can be controlled by varying the electronic and steric properties of the ancillary ligands and that they provide bimetallic sites for the activation and transformation of various substrates. © 1998 Elsevier Science S.A. All rights reserved.
Keywords : Cyclopentadienyl Dimolybdenum Electrochemistry Thiolate Transition metal site X-ray structure
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https://hal.univ-brest.fr/hal-01770742
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Submitted on : Thursday, April 19, 2018 - 10:58:22 AM
Last modification on : Thursday, October 3, 2019 - 8:50:02 AM

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François Pétillon, Philippe Schollhammer, J. Talarmin, K.W. Muir. Dinuclear molybdenum thiolato-bridged compounds: Syntheses, reactivities and electrochemical studies of site-substrate interactions. Coordination Chemistry Reviews, 1998, 178-180, pp.203--247. ⟨hal-01770742⟩

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