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A chromium(III) 2,2′-bipyrimidine (bipym) complex, (Et4N)[Cr(NCS)4-(bipym)]

Abstract : The title structure, tetraethylammonium tetrakis(isothiocyanato)(2,2′-bipyrimidine-N,N′)chromium(III), [(C2H5)4-N][Cr(NCS)4(C 8H6N4)], consists of discrete [Cr(NCS)4-(bipym)]- and [(C2H5)4N]+ ions. The Cr3+ ion lies on a mirror plane and has a regular octahedral coordination polyhedron. The bipym group is planar, with unexceptional bond distances and angles.
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Submitted on : Thursday, April 19, 2018 - 10:09:57 AM
Last modification on : Monday, January 31, 2022 - 4:56:20 PM


  • HAL Id : hal-01770529, version 1



M.T. Garland, R.F. Baggio, F. Berezovsky, Smail Triki, J.S. Pala. A chromium(III) 2,2′-bipyrimidine (bipym) complex, (Et4N)[Cr(NCS)4-(bipym)]. Acta Crystallographica Section C : Crystal Structure Communications [1968-2013], 1997, 53, pp.1803--1805. ⟨hal-01770529⟩



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