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Journal Articles Organometallics Year : 1997

Bridged hemilabile allylphosphonate ligand: Synthesis and crystal structure of a new binuclear rhodium complex

Abstract

The reaction of 2 equiv of the allylphosphonate CH2=CH-CH2-P(O)(OEt)2 with [Rh(Cl)(CO)2]2 results in the formation of a new binuclear rhodium complex with two bridged bidentate allylphosphonate ligands in cis positions, reaction with carbon monoxide induces the lability of the phosphonate moiety, which is reversible.

Dates and versions

hal-01770523 , version 1 (19-04-2018)

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I. Le Gall, P. Laurent, L. Toupet, Jean Yves Salaün, Hervé Des Abbayes. Bridged hemilabile allylphosphonate ligand: Synthesis and crystal structure of a new binuclear rhodium complex. Organometallics, 1997, 16, pp.3579--3581. ⟨10.1021/om970182e⟩. ⟨hal-01770523⟩
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