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Bridged hemilabile allylphosphonate ligand: Synthesis and crystal structure of a new binuclear rhodium complex

Abstract : The reaction of 2 equiv of the allylphosphonate CH2=CH-CH2-P(O)(OEt)2 with [Rh(Cl)(CO)2]2 results in the formation of a new binuclear rhodium complex with two bridged bidentate allylphosphonate ligands in cis positions, reaction with carbon monoxide induces the lability of the phosphonate moiety, which is reversible.
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https://hal.univ-brest.fr/hal-01770523
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Submitted on : Thursday, April 19, 2018 - 10:09:44 AM
Last modification on : Monday, August 31, 2020 - 3:20:12 PM

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I. Le Gall, P. Laurent, L. Toupet, Jean Yves Salaün, Hervé Des Abbayes. Bridged hemilabile allylphosphonate ligand: Synthesis and crystal structure of a new binuclear rhodium complex. Organometallics, American Chemical Society, 1997, 16, pp.3579--3581. ⟨10.1021/om970182e⟩. ⟨hal-01770523⟩

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