Unexpected formation of the novel mixed μ-oxo, μ-sulfido, bis(μ-thiolato) compound [Mo(IV)2Cp2(μ-O)(μ-S)(μ-SMe)2] - Université de Bretagne Occidentale Access content directly
Journal Articles Journal of Organometallic Chemistry Year : 2001

Unexpected formation of the novel mixed μ-oxo, μ-sulfido, bis(μ-thiolato) compound [Mo(IV)2Cp2(μ-O)(μ-S)(μ-SMe)2]

Abstract

A novel example of C-S bond cleavage in a dimolybdenum derivative leads to the formation of the quadruply bridged compound [Mo(IV)2Cp2(μ-O)(μ-S)(μ-SMe)2]. This μ-oxo species is formed by reaction of the chloro-bridged complex [Mo(III)2Cp2(μ-Cl)(μ-SMe)3] with PhCCLi and subsequent hydration at the dimolybdenum site. The Mo-Mo bond length of 2.4900(3)Å in [Mo2Cp2(μ-O)(μ-S)(μ-SMe)2] is unusually short. © 2001 Elsevier Science B.V.

Dates and versions

hal-01770129 , version 1 (18-04-2018)

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Philippe P. Schollhammer, François Pétillon, Jean Talarmin, K.W. Muir. Unexpected formation of the novel mixed μ-oxo, μ-sulfido, bis(μ-thiolato) compound [Mo(IV)2Cp2(μ-O)(μ-S)(μ-SMe)2]. Journal of Organometallic Chemistry, 2001, 627 (1), pp.67-70. ⟨10.1016/S0022-328X(01)00718-5⟩. ⟨hal-01770129⟩
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