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Unexpected formation of the novel mixed μ-oxo, μ-sulfido, bis(μ-thiolato) compound [Mo(IV)2Cp2(μ-O)(μ-S)(μ-SMe)2]

Abstract : A novel example of C-S bond cleavage in a dimolybdenum derivative leads to the formation of the quadruply bridged compound [Mo(IV)2Cp2(μ-O)(μ-S)(μ-SMe)2]. This μ-oxo species is formed by reaction of the chloro-bridged complex [Mo(III)2Cp2(μ-Cl)(μ-SMe)3] with PhCCLi and subsequent hydration at the dimolybdenum site. The Mo-Mo bond length of 2.4900(3)Å in [Mo2Cp2(μ-O)(μ-S)(μ-SMe)2] is unusually short. © 2001 Elsevier Science B.V.
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https://hal.univ-brest.fr/hal-01770129
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Submitted on : Wednesday, April 18, 2018 - 4:15:36 PM
Last modification on : Thursday, October 3, 2019 - 8:50:02 AM

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Philippe Schollhammer, François Pétillon, Jean Talarmin, K.W. Muir. Unexpected formation of the novel mixed μ-oxo, μ-sulfido, bis(μ-thiolato) compound [Mo(IV)2Cp2(μ-O)(μ-S)(μ-SMe)2]. Journal of Organometallic Chemistry, Elsevier, 2001, 627 (1), pp.67-70. ⟨10.1016/S0022-328X(01)00718-5⟩. ⟨hal-01770129⟩

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