Skip to Main content Skip to Navigation
Journal articles

Stoichiometric mono N-functionalization of cyclen via a boron protected intermediate

F. Chuburu M. Le Baccon Henri Handel 1
1 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique
Abstract : The temporary triprotection of cyclen by a boron atom performed in presence of sodium hydride offers a convenient solution for the mono N-alkylation of cyclen. Examples of mono N-alkylated cyclens and bis-cyclens are reported. © 2001 Elsevier Science Ltd.
Keywords : 1 7 10 tetraazacyclododecane boron carbon nitrogen monocycle cyclam sodium derivative sodium hydride unclassified drug alkylation article chemical reaction chemical structure priority journal reaction analysis stoichiometry
Document type :
Journal articles
Complete list of metadatas
https://hal.univ-brest.fr/hal-01770126
Contributor : Nicolas Renard <>
Submitted on : Wednesday, April 18, 2018 - 4:15:30 PM
Last modification on : Friday, February 14, 2020 - 6:02:05 PM

Links full text

istex

Identifiers

Collections

UNIV-BREST | CEMCA-BREST | CNRS | INC-CNRS | IBSAM

Citation

F. Chuburu, M. Le Baccon, Henri Handel. Stoichiometric mono N-functionalization of cyclen via a boron protected intermediate. Tetrahedron, Elsevier, 2001, 57 (12), pp.2385-2390. ⟨10.1016/S0040-4020(01)00115-6⟩. ⟨hal-01770126⟩

Export

BibTeX TEI DC DCterms EndNote

Share

Metrics

Record views

149