Skip to Main content Skip to Navigation
Journal articles

Analysis of chromium and copper by cathodic stripping voltammetry with mixed ligands

Abstract : Cathodic adsorptive stripping voltammetry is one of the most sensitive analytical methods for ultratrace analysis. The detection limit is usually lower than 10-9 mol/L. Most adsorptive stripping procedures have been focused on the one ligand/one analyte approach. In order to reduce analysis time and sample volume, the possibility of simultaneously determining several metals by cathodic stripping voltammetry using a mixture of ligands was explored, e.g., by Colombo and van den Berg (1997). Here, we describe a new procedure for quantifying chromium and copper using 2,2′-bipyridine and 8-hydroxyquinoline (oxine). The effect of various operational parameters such as buffer type, ligand concentration, potential and time collection were assessed and optimized. Possible interferences by trace metals and organic matter were also investigated. Applicability for fresh water is illustrated. © Springer-Verlag 2003.
Complete list of metadatas

https://hal.univ-brest.fr/hal-01763904
Contributor : Nicolas Renard <>
Submitted on : Wednesday, April 11, 2018 - 2:59:26 PM
Last modification on : Friday, October 4, 2019 - 6:00:07 PM

Links full text

Identifiers

Collections

Citation

M. Le Lann, Catherine Elleouet, François Quentel, C.L. Madec. Analysis of chromium and copper by cathodic stripping voltammetry with mixed ligands. Environmental Chemistry Letters, Springer Verlag, 2003, 1 (1), pp.98-102. ⟨10.1007/s10311-002-0013-4⟩. ⟨hal-01763904⟩

Share

Metrics

Record views

111