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A new versatile synthesis of macrotricyclic tetraazacycloalkane-based ligands from bis-aminal derivatives

S. Develay Raphaël Tripier 1 F. Chuburu M. Le Baccon Henri Handel 1
1 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique
Abstract : A new powerful synthesis of symmetrical (two-step) or dissymmetrical (three-step) macrotricyclic cyclen- or cyclam-based ligands is reported. In this procedure, the starting materials are bis-aminals derived from condensation of cyclen or cyclam with glyoxal. The two macrocyclic subunits are linked by two aromatic spacers through nitrogen atoms. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
Keywords : alkane derivative bisaminal derivative cyclam glyoxal heterocyclic amine ligand nitrogen unclassified drug alkylation article chemical structure polymerization reaction analysis structure analysis synthesis
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https://hal.univ-brest.fr/hal-01763899
Contributor : Nicolas Renard <>
Submitted on : Wednesday, April 11, 2018 - 2:59:15 PM
Last modification on : Friday, February 22, 2019 - 4:56:08 PM

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  • HAL Id : hal-01763899, version 1

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S. Develay, Raphaël Tripier, F. Chuburu, M. Le Baccon, Henri Handel. A new versatile synthesis of macrotricyclic tetraazacycloalkane-based ligands from bis-aminal derivatives. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2003, pp.3047-3050. ⟨hal-01763899⟩

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