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Double carbonylation and beyond: Systems at work and their organometallic models

Abstract : A quarter of a century after its (serendipitous) discovery, the catalytic sequential chaining of two carbon monoxides into an organic substrate (the so called double carbonylation reaction), is still not well understood. After a review of the most important experimental results, this Perspective proposes a critical survey of the main organometallic models and outlines some rather neglected tracks. Finally, the issue of the chaining of more than two carbon monoxides is also addressed. © The Royal Society of Chemistry 2003.
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Submitted on : Wednesday, April 11, 2018 - 2:59:06 PM
Last modification on : Thursday, November 29, 2018 - 4:09:15 PM

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Hervé Des Abbayes, Jean-Yves Salaün. Double carbonylation and beyond: Systems at work and their organometallic models. Dalton Transactions, Royal Society of Chemistry, 2003, pp.1041-1052. ⟨10.1039/b209103h⟩. ⟨hal-01763892⟩

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