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Catalysis of the electrochemical H2 evolution by di-iron sub-site models

Abstract : A short non-exhaustive overview of hexacarbonyl dithiolate di-iron species and of their substituted derivatives relevant to the chemistry of the di-iron sub-site of the hydrogenase enzymes is presented. Although few detailed electrochemical studies have been reported until now, we discuss the use of di-iron organometallic species as catalysts for the electrochemical reduction of protons. Finally, we propose targets for the synthesis of more efficient biomimetic catalysts. © 2004 Elsevier B.V. All rights reserved.
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https://hal.univ-brest.fr/hal-01763762
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Submitted on : Wednesday, April 11, 2018 - 1:43:20 PM
Last modification on : Wednesday, September 11, 2019 - 2:14:07 PM

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Jean-François Capon, Frederic Gloaguen, Philippe Schollhammer, Jean Talarmin. Catalysis of the electrochemical H2 evolution by di-iron sub-site models. Coordination Chemistry Reviews, 2005, 249 (15-16 SPEC. ISS.), pp.1664-1676. ⟨10.1016/j.ccr.2004.11.018⟩. ⟨hal-01763762⟩

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