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Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst

Abstract : The base-stabilized silacyclopropylidene 1 behaves as a versatile strongly nucleophilic ligand toward transition metals. The strong silylene−metal binding related to both increased σ-donating and π-accepting character of silylene 1 compared to N-heterocyclic carbenes (NHCs) allowed the synthesis of robust and air-stable silylene complexes. Of particular interest, the corresponding plati-num(0) complex 6 exhibits high stability and a high level of selectivity and catalytic activity in hydrosilylation reactions that is superior to that of the related NHC-Pt 0 complexes.
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https://hal.univ-brest.fr/hal-01646335
Contributor : Thibault Troadec <>
Submitted on : Monday, December 4, 2017 - 11:02:45 AM
Last modification on : Friday, January 17, 2020 - 5:52:07 PM

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Thibault Troadec, Amparo Prades, Ricardo Rodriguez, Raphael Mirgalet, Antoine Baceiredo, et al.. Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst. Inorganic Chemistry, American Chemical Society, 2016, 55 (16), pp.8234-8240. ⟨10.1021/acs.inorgchem.6b01505⟩. ⟨hal-01646335⟩

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