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Journal articles
Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst
Thibault Troadec
1, 2
Amparo Prades
2
Ricardo Rodriguez
2
Raphael Mirgalet
2
Antoine Baceiredo
2
Nathalie Saffon-Merceron
3
Vicenç Branchadell
4
Tsuyoshi Kato
2
Thibault Troadec 1, 2
Author IdHAL : thibaulttroadec ORCID : https://orcid.org/0000-0002-8005-4302
Amparo Prades 2
Author
Ricardo Rodriguez 2
Author
Raphael Mirgalet 2
Author
Antoine Baceiredo 2
Author
Nathalie Saffon-Merceron 3
Author IdHAL : saffon ORCID : https://orcid.org/0000-0002-0301-4163
Vicenç Branchadell 4
Author
Tsuyoshi Kato 2
Author
1
University of Warwick [Coventry] (Coventry CV4 7AL - United Kingdom)
2
LHFA - Laboratoire Hétérochimie Fondamentale et Appliquée (Bâtiment 2R1, 118 Route de Narbonne, 31062 Toulouse - France)
- UT3 - Université Toulouse III - Paul Sabatier (118 route de Narbonne - 31062 Toulouse - France)
- Université Fédérale Toulouse Midi-Pyrénées (41 Allée Jules Guesde, 31000 Toulouse - France)
- CNRS - Centre National de la Recherche Scientifique : UMR5069 (France)
- ICT-FR 2599 - Institut de Chimie de Toulouse (118 Route de Narbonne 31062 Toulouse cédex 9 - France)
- IRD - Institut de Recherche pour le Développement (Siège Le Sextant 44, bd de Dunkerque CS 90009 13572 Marseille cedex 02 - France)
- UT3 - Université Toulouse III - Paul Sabatier (118 route de Narbonne - 31062 Toulouse - France)
- Université Fédérale Toulouse Midi-Pyrénées (41 Allée Jules Guesde, 31000 Toulouse - France)
- CNRS - Centre National de la Recherche Scientifique : UAR2599 / FR2599 (France)
- Toulouse INP - Institut National Polytechnique (Toulouse) (France)
- Université Fédérale Toulouse Midi-Pyrénées (41 Allée Jules Guesde, 31000 Toulouse - France)
3
ICT-FR 2599 - Institut de Chimie de Toulouse (118 Route de Narbonne 31062 Toulouse cédex 9 - France)
- IRD - Institut de Recherche pour le Développement (Siège Le Sextant 44, bd de Dunkerque CS 90009 13572 Marseille cedex 02 - France)
- UT3 - Université Toulouse III - Paul Sabatier (118 route de Narbonne - 31062 Toulouse - France)
- Université Fédérale Toulouse Midi-Pyrénées (41 Allée Jules Guesde, 31000 Toulouse - France)
- CNRS - Centre National de la Recherche Scientifique : UAR2599 / FR2599 (France)
- Toulouse INP - Institut National Polytechnique (Toulouse) (France)
- Université Fédérale Toulouse Midi-Pyrénées (41 Allée Jules Guesde, 31000 Toulouse - France)
4
UAB - Universitat Autònoma de Barcelona (UAB Campus 08193 Bellaterra Barcelona - Spain)
Abstract : The base-stabilized silacyclopropylidene 1 behaves as a versatile strongly nucleophilic ligand toward transition metals. The strong silylene−metal binding related to both increased σ-donating and π-accepting character of silylene 1 compared to N-heterocyclic carbenes (NHCs) allowed the synthesis of robust and air-stable silylene complexes. Of particular interest, the corresponding plati-num(0) complex 6 exhibits high stability and a high level of selectivity and catalytic activity in hydrosilylation reactions that is superior to that of the related NHC-Pt 0 complexes.
Document type :
Journal articles
Complete list of metadata
https://hal.univ-brest.fr/hal-01646335
Contributor : Thibault Troadec Connect in order to contact the contributor
Submitted on : Monday, December 4, 2017 - 11:02:45 AM
Last modification on : Wednesday, September 29, 2021 - 3:01:40 AM
Contributor : Thibault Troadec Connect in order to contact the contributor
Submitted on : Monday, December 4, 2017 - 11:02:45 AM
Last modification on : Wednesday, September 29, 2021 - 3:01:40 AM
Identifiers
- HAL Id : hal-01646335, version 1
- DOI : 10.1021/acs.inorgchem.6b01505
Collections
UNIV-BREST | CNRS | INC-CNRS | UNIV-TLSE3
Citation
Thibault Troadec, Amparo Prades, Ricardo Rodriguez, Raphael Mirgalet, Antoine Baceiredo, et al.. Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst. Inorganic Chemistry, American Chemical Society, 2016, 55 (16), pp.8234-8240. ⟨10.1021/acs.inorgchem.6b01505⟩. ⟨hal-01646335⟩
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