Abstract : The synthesis of donor-stabilized silacyclo-butanone 2 was successfully realized by the reaction of silacyclopropylidene 1 with benzaldehyde in the presence of a Lewis acid catalyst. Of particular interest, silacyclobutanone 2 evolves at room temperature via a retro-[2 + 2]-cycloaddition reaction, leading to an original NHC-stabilized 1-silaketene 4 and cis-stilbene.
Type de document :
Article dans une revue
Journal of the American Chemical Society, American Chemical Society, 2016, 138 (9), pp.2965-2968. 〈10.1021/jacs.6b00631〉
http://hal.univ-brest.fr/hal-01646165
Contributeur : Thibault Troadec
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Soumis le : mardi 5 décembre 2017 - 14:49:07
Dernière modification le : mardi 11 septembre 2018 - 15:19:04
Thibault Troadec, Morelia Lopez, Ricardo Rodriguez, Antoine Baceiredo, Nathalie Saffon-Merceron, et al.. Donor-Stabilized Silacyclobutanone: A Precursor of 1-Silaketene via Retro-[2 + 2]-Cycloaddition Reaction at Room Temperature. Journal of the American Chemical Society, American Chemical Society, 2016, 138 (9), pp.2965-2968. 〈10.1021/jacs.6b00631〉. 〈hal-01646165〉
