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A Stable Silene Substituted by Strong π-Donors at the Silicon Center

Abstract : A stable and isolable silene with two π-donating groups on the silicon center has been synthesized. This silicon-substituted silene shows totally different π-substituent effects compared to those of related carbon-substituted silenes, and it presents intrinsic silene properties with an enhanced electron-donating character, making it an excellent ligand for transition metals.
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https://hal.univ-brest.fr/hal-01646157
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Submitted on : Monday, December 4, 2017 - 11:03:51 AM
Last modification on : Wednesday, November 4, 2020 - 2:36:06 PM

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Norio Nakata, Ricardo Rodriguez, Thibault Troadec, Nathalie Saffon-Merceron, Jean-Marc Sotiropoulos, et al.. A Stable Silene Substituted by Strong π-Donors at the Silicon Center. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2013, 52 (41), pp.10840-10844. ⟨10.1002/anie.201304594⟩. ⟨hal-01646157⟩

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