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Journal Articles Angewandte Chemie International Edition Year : 2013

A Stable Silene Substituted by Strong π-Donors at the Silicon Center

Abstract

A stable and isolable silene with two π-donating groups on the silicon center has been synthesized. This silicon-substituted silene shows totally different π-substituent effects compared to those of related carbon-substituted silenes, and it presents intrinsic silene properties with an enhanced electron-donating character, making it an excellent ligand for transition metals.

Dates and versions

hal-01646157 , version 1 (04-12-2017)

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Norio Nakata, Ricardo Rodriguez, Thibault Troadec, Nathalie Saffon-Merceron, Jean-Marc Sotiropoulos, et al.. A Stable Silene Substituted by Strong π-Donors at the Silicon Center. Angewandte Chemie International Edition, 2013, 52 (41), pp.10840-10844. ⟨10.1002/anie.201304594⟩. ⟨hal-01646157⟩
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