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Journal Articles Angewandte Chemie International Edition Year : 2013

A Base-Stabilized Sila-β-Lactone and a Donor/Acceptor-Stabilized Silanoic Acid

Abstract

A stable base-stabilized sila-β-lactone was successfully synthesized and fully characterized. Interestingly, this sila-β-lactone shows a very unique reactivity toward ethanol, leading to the formation of an isolable donor/acceptor-stabilized silanoic acid.

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Organic chemistry

Thibault Troadec  : Connect in order to contact the contributor

https://hal.univ-brest.fr/hal-01646154

Submitted on : Monday, December 4, 2017-11:03:36 AM

Last modification on : Monday, November 20, 2023-11:44:18 AM

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hal-01646154 , version 1 (04-12-2017)

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Ricardo Rodriguez, David Gau, Thibault Troadec, Nathalie Saffon-Merceron, Vicenç Branchadell, et al.. A Base-Stabilized Sila-β-Lactone and a Donor/Acceptor-Stabilized Silanoic Acid. Angewandte Chemie International Edition, 2013, 52 (34), pp.8980-8983. ⟨10.1002/anie.201304482⟩. ⟨hal-01646154⟩

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UNIV-BREST CNRS INC-CNRS TOULOUSE-INP UNIV-UT3 UT3-TOULOUSEINP LHFA
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