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A Base-Stabilized Sila-β-Lactone and a Donor/Acceptor-Stabilized Silanoic Acid

Abstract : A stable base-stabilized sila-β-lactone was successfully synthesized and fully characterized. Interestingly, this sila-β-lactone shows a very unique reactivity toward ethanol, leading to the formation of an isolable donor/acceptor-stabilized silanoic acid.
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https://hal.univ-brest.fr/hal-01646154
Contributor : Thibault Troadec <>
Submitted on : Monday, December 4, 2017 - 11:03:36 AM
Last modification on : Friday, January 17, 2020 - 5:52:07 PM

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Ricardo Rodriguez, David Gau, Thibault Troadec, Nathalie Saffon-Merceron, Vicenç Branchadell, et al.. A Base-Stabilized Sila-β-Lactone and a Donor/Acceptor-Stabilized Silanoic Acid. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2013, 52 (34), pp.8980-8983. ⟨10.1002/anie.201304482⟩. ⟨hal-01646154⟩

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