A Base-Stabilized Sila-β-Lactone and a Donor/Acceptor-Stabilized Silanoic Acid

Ricardo Rodriguez; David Gau; Thibault Troadec; Nathalie Saffon-Merceron; Vicenç Branchadell; Antoine Baceiredo; Tsuyoshi Kato

doi:10.1002/anie.201304482

Journal articles

A Base-Stabilized Sila-β-Lactone and a Donor/Acceptor-Stabilized Silanoic Acid

Ricardo Rodriguez ¹ David Gau ¹ Thibault Troadec ¹ Nathalie Saffon-Merceron ² Vicenç Branchadell ³ Antoine Baceiredo ¹ Tsuyoshi Kato ¹

1 LHFA - Laboratoire Hétérochimie Fondamentale et Appliquée

2 ICT-FR 2599 - Institut de Chimie de Toulouse

3 departament de Quimica

Abstract : A stable base-stabilized sila-β-lactone was successfully synthesized and fully characterized. Interestingly, this sila-β-lactone shows a very unique reactivity toward ethanol, leading to the formation of an isolable donor/acceptor-stabilized silanoic acid.

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Journal articles

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Chemical Sciences / Organic chemistry

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https://hal.univ-brest.fr/hal-01646154
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Submitted on : Monday, December 4, 2017 - 11:03:36 AM
Last modification on : Thursday, November 24, 2022 - 4:05:30 AM

A Base-Stabilized Sila-β-Lactone and a Donor/Acceptor-Stabilized Silanoic Acid

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A Base-Stabilized Sila-β-Lactone and a Donor/Acceptor-Stabilized Silanoic Acid

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