Complexation of the triphosphate anion: tuning the structure of cyclen based macrotricycles with 1,3-dimethylbenzene and 2,6-dimethylpyridine linkers. A potentiometric and NMR study

Stéphanie Develay 1 Raphaël Tripier 1 Nicolas Bernier 1 Michel Le Baccon 1 Véronique Patinec 1 Guy Serratrice 2 Henri Handel 1
1 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique
2 UMR CNRS 5616
Abstract : The host–guest interaction between orthophosphate, pyrophosphate and triphosphate anions and three cyclen-based macrotricyclic ligands was investigated by potentiometric measurements and NMR spectroscopy. The ligands differ from one another by the nature of their spacers, which are 1,3-dimethylbenzene (TMC), 2,6-dimethylpyridine (TPyC) or a combination of the two (TMPyC). In aqueous solution, each ligand gave protonated species that further formed ternary complexes after binding with anions; these complexes were analyzed as a result of hydrogen bond formation and coulombic attraction between the organic host and the inorganic guest. The equilibrium constants found for all the detected species are reported and the selectivity, illustrated with species distribution diagrams, is discussed. The results unambiguously showed that the ligand possessing a single supplementary anchoring site (the pyridinyl spacer) exhibited the greatest affinity for the phosphate species in a large p[H] range.
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Dalton Transactions, Royal Society of Chemistry, 2007, 〈10.1039/B616862K〉
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http://hal.univ-brest.fr/hal-01581204
Contributeur : Nicolas Renard <>
Soumis le : lundi 4 septembre 2017 - 14:29:18
Dernière modification le : jeudi 11 janvier 2018 - 06:17:06

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Stéphanie Develay, Raphaël Tripier, Nicolas Bernier, Michel Le Baccon, Véronique Patinec, et al.. Complexation of the triphosphate anion: tuning the structure of cyclen based macrotricycles with 1,3-dimethylbenzene and 2,6-dimethylpyridine linkers. A potentiometric and NMR study. Dalton Transactions, Royal Society of Chemistry, 2007, 〈10.1039/B616862K〉. 〈hal-01581204〉

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