First Insights into the Electronic Properties of a Cu(II) Center Embedded in the PN 3 Cap of a Calix[6]arene-Based Ligand - Université de Bretagne Occidentale Access content directly
Journal Articles Inorganic Chemistry Year : 2007

First Insights into the Electronic Properties of a Cu(II) Center Embedded in the PN 3 Cap of a Calix[6]arene-Based Ligand

Abstract

The first metal complex based on the calix[6]PN3 cryptand is described. The solid-state and solution studies show a 5-coordinate Cu(II) center due to its coordination to the PN3 cap and to an exchangeable guest molecule. Spectroscopic and electrochemical studies evidence surprising properties of the metal ion, which are tentatively assigned to the unusual P−Cu(II) bond enforced by the cryptand.

Dates and versions

hal-01581200 , version 1 (04-09-2017)

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G. Izzet, X. Zeng, D. Over, Bénédicte Douziech, J. Zeitouny, et al.. First Insights into the Electronic Properties of a Cu(II) Center Embedded in the PN 3 Cap of a Calix[6]arene-Based Ligand. Inorganic Chemistry, 2007, 46 (2), pp.375 - 377. ⟨10.1021/ic0620384⟩. ⟨hal-01581200⟩
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