First Insights into the Electronic Properties of a Cu(II) Center Embedded in the PN 3 Cap of a Calix[6]arene-Based Ligand

Abstract : The first metal complex based on the calix[6]PN3 cryptand is described. The solid-state and solution studies show a 5-coordinate Cu(II) center due to its coordination to the PN3 cap and to an exchangeable guest molecule. Spectroscopic and electrochemical studies evidence surprising properties of the metal ion, which are tentatively assigned to the unusual P−Cu(II) bond enforced by the cryptand.
Type de document :
Article dans une revue
Inorganic Chemistry, American Chemical Society, 2007, 46 (2), pp.375 - 377. 〈10.1021/ic0620384〉
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http://hal.univ-brest.fr/hal-01581200
Contributeur : Nicolas Renard <>
Soumis le : lundi 4 septembre 2017 - 14:26:29
Dernière modification le : vendredi 31 août 2018 - 09:03:53

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G. Izzet, X. Zeng, D. Over, Bénédicte Douziech, J. Zeitouny, et al.. First Insights into the Electronic Properties of a Cu(II) Center Embedded in the PN 3 Cap of a Calix[6]arene-Based Ligand. Inorganic Chemistry, American Chemical Society, 2007, 46 (2), pp.375 - 377. 〈10.1021/ic0620384〉. 〈hal-01581200〉

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