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An Efficient and Straightforward Access to Sulfur Substituted [2.2]Paracyclophanes: Application to Stereoselective Sulfenate Salt Alkylation

Abstract : A straightforward and high-yielding access to various [2.2]paracyclophanes possessing a sulfur-based functional group is reported, the key step being a SEAr reaction mediated by a sulfonium salt. The versatility of the methodology was exemplified by an original application in sulfenate salt chemistry, from which a remarkable chirality transfer was observed.
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https://hal.univ-brest.fr/hal-01580460
Contributor : Nicolas Renard <>
Submitted on : Friday, September 1, 2017 - 3:26:20 PM
Last modification on : Friday, September 11, 2020 - 3:00:03 PM

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Jean-François Lohier, Florian Foucoin, Paul-Alain Jaffres, José I. Garcia, Jana Sopkova-de Oliveira Santos, et al.. An Efficient and Straightforward Access to Sulfur Substituted [2.2]Paracyclophanes: Application to Stereoselective Sulfenate Salt Alkylation. Organic Letters, American Chemical Society, 2008, 10 (6), pp.1271 - 1274. ⟨10.1021/ol800161m⟩. ⟨hal-01580460⟩

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