An Efficient and Straightforward Access to Sulfur Substituted [2.2]Paracyclophanes: Application to Stereoselective Sulfenate Salt Alkylation - Université de Bretagne Occidentale Access content directly
Journal Articles Organic Letters Year : 2008

An Efficient and Straightforward Access to Sulfur Substituted [2.2]Paracyclophanes: Application to Stereoselective Sulfenate Salt Alkylation

Abstract

A straightforward and high-yielding access to various [2.2]paracyclophanes possessing a sulfur-based functional group is reported, the key step being a SEAr reaction mediated by a sulfonium salt. The versatility of the methodology was exemplified by an original application in sulfenate salt chemistry, from which a remarkable chirality transfer was observed.
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hal-01580460 , version 1 (01-09-2017)

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Jean-François Lohier, Florian Foucoin, Paul-Alain Jaffres, José I. Garcia, Jana Sopkova-de Oliveira Santos, et al.. An Efficient and Straightforward Access to Sulfur Substituted [2.2]Paracyclophanes: Application to Stereoselective Sulfenate Salt Alkylation. Organic Letters, 2008, 10 (6), pp.1271 - 1274. ⟨10.1021/ol800161m⟩. ⟨hal-01580460⟩
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