Bismuth(III) complexes with tetra-pyridylmethyl-cyclen

Abstract : Bimuth(III) complexes with 1,4,7,10-tetrakis(2-pyridylmethyl)-1,4,7,10-tetraazacyclododecane have been prepared in dichloromethane and ethanol and investigated. These complexes have been characterized structurally by X-ray diffraction and NMR-2D studies. They present different coordination scheme depending on the reaction conditions: according to the nature of solvent, bismuth coordinates from six to eight nitrogen atoms and forms in the solid state a chiral structure which is maintained in solution.
Type de document :
Article dans une revue
Inorganica Chimica Acta Reviews, Elsevier, 2009, 362 (6), pp.1781 - 1786. 〈10.1016/j.ica.2008.08.013〉
Liste complète des métadonnées

http://hal.univ-brest.fr/hal-01580209
Contributeur : Nicolas Renard <>
Soumis le : vendredi 1 septembre 2017 - 10:59:38
Dernière modification le : jeudi 11 janvier 2018 - 06:17:06

Identifiants

Collections

Citation

Jean-François Morfin, Raphaël Tripier, Michel Le Baccon, Henri Handel. Bismuth(III) complexes with tetra-pyridylmethyl-cyclen. Inorganica Chimica Acta Reviews, Elsevier, 2009, 362 (6), pp.1781 - 1786. 〈10.1016/j.ica.2008.08.013〉. 〈hal-01580209〉

Partager

Métriques

Consultations de la notice

62