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Bismuth(III) complexes with tetra-pyridylmethyl-cyclen

Abstract : Bimuth(III) complexes with 1,4,7,10-tetrakis(2-pyridylmethyl)-1,4,7,10-tetraazacyclododecane have been prepared in dichloromethane and ethanol and investigated. These complexes have been characterized structurally by X-ray diffraction and NMR-2D studies. They present different coordination scheme depending on the reaction conditions: according to the nature of solvent, bismuth coordinates from six to eight nitrogen atoms and forms in the solid state a chiral structure which is maintained in solution.
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Jean-François Morfin, Raphaël Tripier, Michel Le Baccon, Henri Handel. Bismuth(III) complexes with tetra-pyridylmethyl-cyclen. Inorganica Chimica Acta Reviews, 2009, 362 (6), pp.1781 - 1786. ⟨10.1016/j.ica.2008.08.013⟩. ⟨hal-01580209⟩



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