Electron and proton transfers at diiron dithiolate sites relevant to the catalysis of proton reduction by the [FeFe]-hydrogenases

Abstract : This review focuses on electron and proton transfers involving hexacarbonyl and substituted {2Fe2S} complexes inspired from the active site of the [FeFe]-hydrogenases ([FeFe]H2ases), and on different mechanisms by which the synthetic models catalyze the reduction of protons. Selected aspects of the mechanisms proposed for the biological process on the basis of DFT calculations are also briefly presented.
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Article dans une revue
Coordination Chemistry Reviews, Elsevier, 2009, 253 (9-10), pp.1476 - 1494. 〈http://www.sciencedirect.com/science/article/pii/S0010854508002026〉. 〈10.1016/j.ccr.2008.10.020〉
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http://hal.univ-brest.fr/hal-01578087
Contributeur : Nicolas Renard <>
Soumis le : lundi 28 août 2017 - 16:19:50
Dernière modification le : mercredi 11 avril 2018 - 10:56:01

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Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, Philippe Schollhammer, Jean Talarmin. Electron and proton transfers at diiron dithiolate sites relevant to the catalysis of proton reduction by the [FeFe]-hydrogenases. Coordination Chemistry Reviews, Elsevier, 2009, 253 (9-10), pp.1476 - 1494. 〈http://www.sciencedirect.com/science/article/pii/S0010854508002026〉. 〈10.1016/j.ccr.2008.10.020〉. 〈hal-01578087〉

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