Isomerism as a remarkable tool for the design of new potentially bridging macrocycle ligands: Synthesis and characterization of the [Cu(4-L1)](NO3)2·2H2O polymeric chain (4-L1=mono-N (4-picolyl)cyclen)

Fatima El Hajj; Véronique Patinec; Smail Triki; Henri Handel; Mathieu Marchivie

doi:10.1016/j.inoche.2010.07.024

Journal articles

Isomerism as a remarkable tool for the design of new potentially bridging macrocycle ligands: Synthesis and characterization of the [Cu(4-L1)](NO3)2·2H2O polymeric chain (4-L1=mono-N (4-picolyl)cyclen)

Fatima El Hajj ¹ Véronique Patinec ¹ Smail Triki ¹ Henri Handel ¹ Mathieu Marchivie ¹

1 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique

Abstract : A new coordination complex [Cu(4-L1)](NO3)2.2H2O (1) based on the mono-N (4-picolyl)cyclen (4-L1) has been prepared and characterized by X-ray diffraction. The structure of 1 can be described as a monodimensional coordination polymer in which the macrocycle ligand acts as bridging ligand.

Keywords : Coordination polymer Bridging ligand Functionalized macrocycle ligand Copper(II) complexes

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Journal articles

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Chemical Sciences

Chemical Sciences / Inorganic chemistry

Chemical Sciences / Coordination chemistry

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Isomerism as a remarkable tool for the design of new potentially bridging macrocycle ligands: Synthesis and characterization of the [Cu(4-L1)](NO3)2·2H2O polymeric chain (4-L1=mono-N (4-picolyl)cyclen)

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Isomerism as a remarkable tool for the design of new potentially bridging macrocycle ligands: Synthesis and characterization of the [Cu(4-L1)](NO3)2·2H2O polymeric chain (4-L1=mono-N (4-picolyl)cyclen)

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