Isomerism as a remarkable tool for the design of new potentially bridging macrocycle ligands: Synthesis and characterization of the [Cu(4-L1)](NO3)2·2H2O polymeric chain (4-L1=mono-N (4-picolyl)cyclen)

Fatima El Hajj 1 Véronique Patinec 1 Smail Triki 1 Henri Handel 1 Mathieu Marchivie 1
1 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique
Abstract : A new coordination complex [Cu(4-L1)](NO3)2.2H2O (1) based on the mono-N (4-picolyl)cyclen (4-L1) has been prepared and characterized by X-ray diffraction. The structure of 1 can be described as a monodimensional coordination polymer in which the macrocycle ligand acts as bridging ligand.
Keywords : Coordination polymer Bridging ligand Functionalized macrocycle ligand Copper(II) complexes
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Article dans une revue
Inorganic Chemistry Communications, Elsevier, 2010, 13 (11), pp.1314 - 1316. 〈10.1016/j.inoche.2010.07.024〉
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http://hal.univ-brest.fr/hal-01577428
Contributeur : Nicolas Renard <>
Soumis le : vendredi 25 août 2017 - 16:12:08
Dernière modification le : jeudi 11 janvier 2018 - 06:17:06

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Fatima El Hajj, Véronique Patinec, Smail Triki, Henri Handel, Mathieu Marchivie. Isomerism as a remarkable tool for the design of new potentially bridging macrocycle ligands: Synthesis and characterization of the [Cu(4-L1)](NO3)2·2H2O polymeric chain (4-L1=mono-N (4-picolyl)cyclen). Inorganic Chemistry Communications, Elsevier, 2010, 13 (11), pp.1314 - 1316. 〈10.1016/j.inoche.2010.07.024〉. 〈hal-01577428〉

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