Isomerism as a remarkable tool for the design of new potentially bridging macrocycle ligands: Synthesis and characterization of the [Cu(4-L1)](NO3)2·2H2O polymeric chain (4-L1=mono-N (4-picolyl)cyclen)

A new coordination complex [Cu(4-L1)](NO3)2.2H2O (1) based on the mono-N (4-picolyl)cyclen (4-L1) has been prepared and characterized by X-ray diffraction. The structure of 1 can be described as a monodimensional coordination polymer in which the macrocycle ligand acts as bridging ligand.

Keywords

Coordination polymer Bridging ligand Functionalized macrocycle ligand Copper(II) complexes

Domains

Chemical Sciences Inorganic chemistry Coordination chemistry

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https://hal.univ-brest.fr/hal-01577428

Submitted on : Friday, August 25, 2017-4:12:08 PM

Last modification on : Monday, November 6, 2023-12:08:27 PM

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hal-01577428 , version 1 (25-08-2017)

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HAL Id : hal-01577428 , version 1
DOI : 10.1016/j.inoche.2010.07.024

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Fatima El Hajj, Véronique Patinec, Smail Triki, Henri Handel, Mathieu Marchivie. Isomerism as a remarkable tool for the design of new potentially bridging macrocycle ligands: Synthesis and characterization of the [Cu(4-L1)](NO3)2·2H2O polymeric chain (4-L1=mono-N (4-picolyl)cyclen). Inorganic Chemistry Communications, 2010, 13 (11), pp.1314 - 1316. ⟨10.1016/j.inoche.2010.07.024⟩. ⟨hal-01577428⟩

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