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Isomerism as a remarkable tool for the design of new potentially bridging macrocycle ligands: Synthesis and characterization of the [Cu(4-L1)](NO3)2·2H2O polymeric chain (4-L1=mono-N (4-picolyl)cyclen)

Abstract : A new coordination complex [Cu(4-L1)](NO3)2.2H2O (1) based on the mono-N (4-picolyl)cyclen (4-L1) has been prepared and characterized by X-ray diffraction. The structure of 1 can be described as a monodimensional coordination polymer in which the macrocycle ligand acts as bridging ligand.
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https://hal.univ-brest.fr/hal-01577428
Contributor : Nicolas Renard <>
Submitted on : Friday, August 25, 2017 - 4:12:08 PM
Last modification on : Wednesday, July 15, 2020 - 10:30:02 AM

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Fatima El Hajj, Véronique Patinec, Smail Triki, Henri Handel, Mathieu Marchivie. Isomerism as a remarkable tool for the design of new potentially bridging macrocycle ligands: Synthesis and characterization of the [Cu(4-L1)](NO3)2·2H2O polymeric chain (4-L1=mono-N (4-picolyl)cyclen). Inorganic Chemistry Communications, Elsevier, 2010, 13 (11), pp.1314 - 1316. ⟨10.1016/j.inoche.2010.07.024⟩. ⟨hal-01577428⟩

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