Diiron species containing a cyclic P Ph 2 N Ph 2 diphosphine related to the [FeFe]H 2 ases active site

Abstract : A new dissymmetrically disubstituted diiron dithiolate species, [Fe2(CO)4(κ2-PPh2NPh2)(μ-pdt)] (pdt = S(CH2)3S), was prepared by using a flexible cyclic base-containing diphosphine, 1,3,5,7-tetraphenyl 1,5-diaza-3,7-diphosphacyclooctane (PPh2NPh2 = {PhPCH2NPh}2). Preliminary investigations of proton and electron transfers on the diiron system have been done.
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Chemical Communications, Royal Society of Chemistry, 2011, 47 (3), pp.878 - 880. 〈10.1039/C0CC03295F〉
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Soumis le : jeudi 24 août 2017 - 15:46:33
Dernière modification le : mercredi 11 avril 2018 - 10:56:01

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Sondès Lounissi, Jean-François Capon, Frederic Gloaguen, Fatma Matoussi, François Y. Pétillon, et al.. Diiron species containing a cyclic P Ph 2 N Ph 2 diphosphine related to the [FeFe]H 2 ases active site. Chemical Communications, Royal Society of Chemistry, 2011, 47 (3), pp.878 - 880. 〈10.1039/C0CC03295F〉. 〈hal-01577005〉

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