Diiron species containing a cyclic P Ph 2 N Ph 2 diphosphine related to the [FeFe]H 2 ases active site - Université de Bretagne Occidentale Access content directly
Journal Articles Chemical Communications Year : 2011

Diiron species containing a cyclic P Ph 2 N Ph 2 diphosphine related to the [FeFe]H 2 ases active site

Abstract

A new dissymmetrically disubstituted diiron dithiolate species, [Fe2(CO)4(κ2-PPh2NPh2)(μ-pdt)] (pdt = S(CH2)3S), was prepared by using a flexible cyclic base-containing diphosphine, 1,3,5,7-tetraphenyl 1,5-diaza-3,7-diphosphacyclooctane (PPh2NPh2 = {PhPCH2NPh}2). Preliminary investigations of proton and electron transfers on the diiron system have been done.
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Dates and versions

hal-01577005 , version 1 (24-08-2017)

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Sondès Lounissi, Jean-François Capon, Frederic Gloaguen, Fatma Matoussi, François Y. Pétillon, et al.. Diiron species containing a cyclic P Ph 2 N Ph 2 diphosphine related to the [FeFe]H 2 ases active site. Chemical Communications, 2011, 47 (3), pp.878 - 880. ⟨10.1039/C0CC03295F⟩. ⟨hal-01577005⟩
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