Skip to Main content Skip to Navigation
Journal articles

Diiron species containing a cyclic P Ph 2 N Ph 2 diphosphine related to the [FeFe]H 2 ases active site

Abstract : A new dissymmetrically disubstituted diiron dithiolate species, [Fe2(CO)4(κ2-PPh2NPh2)(μ-pdt)] (pdt = S(CH2)3S), was prepared by using a flexible cyclic base-containing diphosphine, 1,3,5,7-tetraphenyl 1,5-diaza-3,7-diphosphacyclooctane (PPh2NPh2 = {PhPCH2NPh}2). Preliminary investigations of proton and electron transfers on the diiron system have been done.
Document type :
Journal articles
Complete list of metadatas

https://hal.univ-brest.fr/hal-01577005
Contributor : Nicolas Renard <>
Submitted on : Thursday, August 24, 2017 - 3:46:33 PM
Last modification on : Thursday, October 3, 2019 - 8:50:07 AM

Identifiers

Collections

Citation

Sondès Lounissi, Jean-François Capon, Frederic Gloaguen, Fatma Matoussi, François Y. Pétillon, et al.. Diiron species containing a cyclic P Ph 2 N Ph 2 diphosphine related to the [FeFe]H 2 ases active site. Chemical Communications, Royal Society of Chemistry, 2011, 47 (3), pp.878 - 880. ⟨10.1039/C0CC03295F⟩. ⟨hal-01577005⟩

Share

Metrics

Record views

201