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Diiron species containing a cyclic P Ph 2 N Ph 2 diphosphine related to the [FeFe]H 2 ases active site

Sondès Lounissi 1 Jean-François Capon 2 Frederic Gloaguen 2 Fatma Matoussi 1 François Y. Pétillon 2 Philippe Schollhammer 2 Jean Talarmin 2
1 Chemical and Biological Engineering Department
2 CEMCA - Chimie, Electrochimie Moléculaires et Chimie Analytique
Abstract : A new dissymmetrically disubstituted diiron dithiolate species, [Fe2(CO)4(κ2-PPh2NPh2)(μ-pdt)] (pdt = S(CH2)3S), was prepared by using a flexible cyclic base-containing diphosphine, 1,3,5,7-tetraphenyl 1,5-diaza-3,7-diphosphacyclooctane (PPh2NPh2 = {PhPCH2NPh}2). Preliminary investigations of proton and electron transfers on the diiron system have been done.
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https://hal.univ-brest.fr/hal-01577005
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Submitted on : Thursday, August 24, 2017 - 3:46:33 PM
Last modification on : Monday, October 11, 2021 - 2:22:08 PM

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UNIV-BREST | CNRS | CEMCA-BREST | INC-CNRS | IBSAM

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Sondès Lounissi, Jean-François Capon, Frederic Gloaguen, Fatma Matoussi, François Y. Pétillon, et al.. Diiron species containing a cyclic P Ph 2 N Ph 2 diphosphine related to the [FeFe]H 2 ases active site. Chemical Communications, Royal Society of Chemistry, 2011, 47 (3), pp.878 - 880. ⟨10.1039/C0CC03295F⟩. ⟨hal-01577005⟩

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