J. Wachter, BIS(CYCLOPENTADIENYL TRANSITION METAL) COMPLEXES RICH IN SULFUR, Journal of Coordination Chemistry, vol.40, issue.3, pp.219-236, 1987.
DOI : 10.1002/anie.198404381

M. R. Dubois, Catalytic applications of transition-metal complexes with sulfide ligands, Chemical Reviews, vol.89, issue.1, pp.1-9, 1989.
DOI : 10.1021/cr00091a001

M. D. Curtis, Molybdenum/cobalt/sulfur clusters: Models and precursors for hydrodesulfurization (HDS) catalysts, Applied Organometallic Chemistry, vol.75, issue.5, pp.429-436, 1992.
DOI : 10.1002/aic.690350112

R. Poli, MONOCYCLOPENTADIENYLMOLYBDENUM(III) CHEMISTRY, Journal of Coordination Chemistry, vol.22, issue.1-2, pp.121-173, 1993.
DOI : 10.1021/j100661a017

T. Shibahara, Syntheses of sulphur-bridged molybdenum and tungsten coordination compounds, Coordination Chemistry Reviews, vol.123, issue.1-2, pp.73-147, 1993.
DOI : 10.1016/0010-8545(93)85053-7

R. Poli, High Oxidation State Organometallic Chemistry in Aqueous Media: New Opportunities for Catalysis and Electrocatalysis, Chemistry - A European Journal, vol.10, issue.2, pp.332-341, 2004.
DOI : 10.1002/chem.200304810

D. Mohr, H. Wienand, and M. L. Ziegler, Darstellung und charakterisierung von zweikern-komplexen der zusammensetzung ??7-C7H7Mo-??-(ER)3Mo(CO)3 (E ??? S, Se), (??7-C7H7)(CO)Mo-??-(TeC6H5)2Mo(CO)(??7-C7H7) und (??3-C7H7)(CO)2Mo-??-(OR)3Mo(??7-C7H7), Journal of Organometallic Chemistry, vol.134, issue.3, pp.281-296, 1977.
DOI : 10.1016/S0022-328X(00)93275-3

F. Y. Pétillon, J. Quéré, J. Roué, J. E. Guerchais, and D. W. Sharp, Molybdenum alkyl- and aryl-thiolates, Journal of Organometallic Chemistry, vol.204, issue.2, pp.207-210, 1981.
DOI : 10.1016/S0022-328X(00)84586-6

T. Hsieh and J. Zubieta, The preparation of binuclear bis-diazenido complexes of molybdenum. The structure of (HNEt3) [Mo2(NNC6H5)4(SC6H5], a triply-thiolato-bridged species with an unsually long Mo???Mo distance, Inorganica Chimica Acta, vol.99, issue.2, pp.47-49, 1985.
DOI : 10.1016/S0020-1693(00)87954-2

D. S. Tucker, S. Dietz, K. G. Parker, V. Carperos, J. Gabay et al., Substitution reactions of a .mu.-thioether ligand in dinuclear cyclopentadienylmolybdenum complexes, Organometallics, vol.14, issue.9, pp.4325-4333, 1995.
DOI : 10.1021/om00009a041

R. S. Dickson, G. D. Fallon, W. R. Jackson, and A. Polas, Formation and structures of novel polynuclear complexes containing Mo???Mo or Mo???Co bonds with bridging SR or PR2 group, Journal of Organometallic Chemistry, vol.607, issue.1-2, pp.156-163, 2000.
DOI : 10.1016/S0022-328X(00)00307-7

F. Demirhan, G. Taban, M. Baya, C. Dinoi, J. Daran et al., Reduction of by thioglycolic acid in an aqueous medium: Synthesis and structure of [{Cp*Mo(??-SCH2COO)}2(??-S)], Journal of Organometallic Chemistry, vol.691, issue.4, pp.648-654, 2006.
DOI : 10.1016/j.jorganchem.2005.10.006

D. García-vivo, A. Ramos, and M. A. Ruiz, Cyclopentadienyl and related complexes of the group 6 elements having metal???metal triple bonds: Synthesis, structure, bonding and reactivity, Coordination Chemistry Reviews, vol.257, issue.15-16, pp.2143-2191, 2013.
DOI : 10.1016/j.ccr.2013.03.026

M. B. Gomes-de-lima, J. E. Guerchais, R. Mercier, and F. Y. Pétillon, Reactions of bimetallic group VI (6) complexes. 3. Synthesis, characterization and reactivity of dimeric molybdenum(III) and tungsten(III) compounds with bridging thiolate ligands. A molybdenum-95 NMR study on dinuclear molybdenum complexes. Crystal structure of [Mo2III(.eta.5-C5H5)2(SMe)3(CO)2]Br.cntdot.H2O, Organometallics, vol.5, issue.10, pp.1952-1964, 1986.
DOI : 10.1021/om00141a005

P. Schollhammer, E. Guénin, F. Y. Pétillon, J. Talarmin, K. W. Muir et al., }, Organometallics, vol.17, issue.10, pp.1922-1924, 1998.
DOI : 10.1021/om971114v

J. Capon, P. Schollhammer, F. Y. Pétillon, J. Talarmin, and K. W. Muir, Coordination of a Thiophenium Cation, Organometallics, vol.18, issue.11, pp.2055-2057, 1999.
DOI : 10.1021/om9900972

). P. Schollhammer, F. Y. Pétillon, J. Talarmin, and K. W. Muir, The effect of replacing carbonyl with acetonitrile on the reactivity of the bimetallic system [Mo2Cp2(??-SMe)3(L)2]+ (L=CO, CH3CN). Crystal structure of [Mo2Cp2(??-SMe)2(CH3CN)4](BF4)2, Inorganica Chimica Acta, vol.284, issue.1, pp.107-111, 1996.
DOI : 10.1016/S0020-1693(98)00266-7

J. Cabon, C. L. Roy, K. W. Muir, F. Y. Pétillon, F. Quentel et al., Electrochemical Reduction of a Bridging Imide: Generation of Ammonia at a Dimolybdenum Tris(??-thiolate) Site, Chemistry - A European Journal, vol.6, issue.16, pp.3033-3042, 2000.
DOI : 10.1002/1521-3765(20000818)6:16<3033::AID-CHEM3033>3.0.CO;2-A

P. Schollhammer, N. Cabon, J. Capon, F. Y. Pétillon, J. Talarmin et al., -Vinyl???Thioether Compounds, Organometallics, vol.20, issue.6, pp.1230-1242, 2001.
DOI : 10.1021/om000966j

N. Le-grand, K. W. Muir, F. Y. Pétillon, C. J. Pickett, and P. Schollhammer, Electrochemical Cleavage of NdN Bonds at a Mo2(??-SMe)3 Site Relevant to the Biological Reduction of Dinitrogen at a Bimetallic Sulfur Centre, Chemistry - A European Journal, vol.8, issue.14, pp.3115-3127, 2002.
DOI : 10.1002/1521-3765(20020715)8:14<3115::AID-CHEM3115>3.0.CO;2-Z

P. Schollhammer, N. Cabon, A. Kervella, F. Y. Pétillon, R. Rumin et al., Incorporation of alkyne and vinylidene ligands into tetrazolate groups at a sulfur-rich dimolybdenum site using sodium azide, Inorganica Chimica Acta, vol.350, pp.495-502, 2003.
DOI : 10.1016/S0020-1693(02)01556-6

A. L. Goff, C. L. Roy, F. Y. Pétillon, P. Schollhammer, and J. Talarmin, } site and protonation of the oxidized diazenido complex, New J. Chem., vol.36, issue.180, pp.929-938, 2006.
DOI : 10.1063/1.1732849

W. Ojo, F. Y. Pétillon, P. Schollhammer, J. Talarmin, and K. W. Muir, A Bridging Side-on Allenylidene Dimolybdenum Complex without Carbonyl Stabilization, Organometallics, vol.25, issue.22, pp.5503-5505, 2006.
DOI : 10.1021/om060663a
URL : https://hal.archives-ouvertes.fr/hal-01582977

J. K. Padden-metzker and J. E. Mcgrady, An Electronic Perspective on the Reduction of an N?N Double Bond at a Conserved Dimolybdenum Core, Chemistry - A European Journal, vol.82, issue.180, pp.6447-6455, 2004.
DOI : 10.1016/0021-9991(92)90277-6

F. Barrière, C. F. Barrière, M. C. Durrant, and C. J. Pickett, Catalysts for Nitrogen Fixation: Nitrogenases, Relevant Chemical Models, and Commercial Processes Bioinspired Catalysis; Metal-Sulfur Complexes, Part III ''Nitrogen Fixation, Encyclopedia of Electrochemistry, pp.71-89, 2003.

P. Schollhammer, F. Y. Pétillon, J. Talarmin, and K. W. Muir, A dimolybdenum(III) azido compound: its decomposition into amido and nitrido derivatives. Crystal structure of [Mo3(O)(N)Cp3(SMe)4], Journal of Organometallic Chemistry, vol.560, issue.1-2, pp.245-251, 1998.
DOI : 10.1016/S0022-328X(98)00516-6

P. Schollhammer, F. Y. Pétillon, J. Talarmin, and K. W. Muir, Unexpected formation of the novel mixed ??-oxo, ??-sulfido, bis(??-thiolato) compound [Mo(IV)2Cp2(??-O)(??-S)(??-SMe)2], Journal of Organometallic Chemistry, vol.627, issue.1, pp.67-70, 2001.
DOI : 10.1016/S0022-328X(01)00718-5

N. Cabon, P. Schollhammer, F. Y. Pétillon, J. Talarmin, and K. W. Muir, ??-Alkylidyne and ??-Alkylidene Complexes from a Bridging Side-on Vinylidene Sulfur-Rich Dimolybdenum Precursor, Organometallics, vol.21, issue.3, pp.448-450, 2002.
DOI : 10.1021/om010853f

N. Cabon, E. Paugam, F. Y. Pétillon, P. Schollhammer, J. Talarmin et al., } Nucleus, Organometallics, vol.22, issue.21, pp.4178-4180, 2003.
DOI : 10.1021/om030447r

N. Cabon, A. L. Goff, C. L. Roy, F. Y. Pétillon, P. Schollhammer et al., }:?? Chemical and Electrochemical Formation of ??-Alkyl and ??-Vinyl Compounds from a ??-Alkylidene Derivative, Organometallics, vol.24, issue.25, pp.6268-6278, 2005.
DOI : 10.1021/om050761g

N. Cabon, F. Y. Pétillon, P. Schollhammer, J. Talarmin, and K. W. Muir, Methylation sites in tris(??-thiolato)dimolybdenum(III) complexes, Journal of Organometallic Chemistry, vol.691, issue.4, pp.566-572, 2006.
DOI : 10.1016/j.jorganchem.2005.09.042
URL : https://hal.archives-ouvertes.fr/hal-01582159

W. Ojo, E. Paugam, F. Y. Pétillon, P. Schollhammer, J. Talarmin et al., Formation of C???C, C???N, and C???O Links between Isonitrile, Cyclopentadienyl, and Hydroxide Ligands Bound to Molybdenum(III):?? Syntheses and Crystal Structures of ??-Aminocarbyne and ??-Amino-oxycarbene Dimolybdenum Complexes, Organometallics, vol.25, issue.16, pp.4009-4018, 2006.
DOI : 10.1021/om060383v

W. Ojo, F. Y. Pétillon, P. Schollhammer, and J. Talarmin, -BuNC, CO, MeCN), Organometallics, vol.27, issue.16, pp.4207-4222, 2008.
DOI : 10.1021/om8003702

W. Ojo, J. E. Mcgrady, F. Y. Pétillon, P. Schollhammer, and J. Talarmin, ], Organometallics, vol.30, issue.3, pp.649-652, 2011.
DOI : 10.1021/om101061y

Y. Chen, Y. Zhou, P. Chen, Y. Tao, Y. Li et al., ): Synthesis, Structure, and Catalytic N???N Bond Cleavage of Hydrazines on Diiron Centers, Journal of the American Chemical Society, vol.130, issue.46, pp.15250-15251, 2008.
DOI : 10.1021/ja805025w

Y. Chen, Y. Zhou, and J. Qu, ; R = Et, Ph), Organometallics, vol.27, issue.4, pp.666-671, 2008.
DOI : 10.1021/om0611148

F. Takagi, H. Seino, Y. Mizobe, and M. Hidai, sulfido-cyanoethylthiolato cluster, Canadian Journal of Chemistry, vol.33, issue.5-6, pp.632-634, 2001.
DOI : 10.1021/ar990016y

F. Takagi, H. Seino, Y. Mizobe, and M. Hidai, Synthesis of a New Tetrakis(hydrosulfido) Diiridium Complex and Its Conversion into Homo- and Heterometallic Sulfido???Hydrosulfido Clusters, Organometallics, vol.21, issue.4, pp.694-699, 2002.
DOI : 10.1021/om0108550

F. Takagi, H. Seino, Y. Mizobe, and M. Hidai, Cl] and Its Transformations into Alkyne, CO, Isocyanide, and Iminoacyl Clusters, Organometallics, vol.22, issue.5, pp.1065-1071, 2003.
DOI : 10.1021/om0208117

W. Schulze and M. L. Ziegler, Darstellung und Charakterisierung von Wolframkomplexen mit ER?-Liganden; E = O, S, Se, Te; R = Alkyl, Aryl, Zeitschrift f???r anorganische und allgemeine Chemie, vol.38, issue.10, pp.78-94, 1981.
DOI : 10.1002/zaac.19814811010

Z. Xu and Z. Lin, Transition metal tetrahydroborato complexes: an orbital interaction analysis of their structure and bonding, Coordination Chemistry Reviews, vol.156, pp.139-162, 1996.
DOI : 10.1016/S0010-8545(96)01254-4

T. M. Gilbert, F. J. Hollander, and R. G. Bergman, (Pentamethylcyclopentadienyl)iridium polyhydride complexes: synthesis of intermediates in the mechanism of formation of (pentamethylcyclopentadienyl)iridium tetrahydride and the preparation of several iridium(V) compounds, Journal of the American Chemical Society, vol.107, issue.12, pp.3508-3516, 1985.
DOI : 10.1021/ja00298a018

M. Jancke, G. Mester, G. Rheiwald, H. Stoekli-evans, and G. Süss-fink, ), Organometallics, vol.16, issue.6, pp.1137-1143, 1997.
DOI : 10.1021/om960840f

C. J. Pickett, The Chatt cycle and the mechanism of enzymic reduction of molecular nitrogen, Journal of Biological Inorganic Chemistry, vol.1, issue.6, pp.601-606, 1996.
DOI : 10.1007/s007750050099

S. Kuwata, Y. Mizobe, and M. Hidai, Catalytic N-N Bond Cleavage of Hydrazines at the Coordinatively Unsaturated Diruthenium Center in [Cp*Ru(.mu.-SR)2RuCp*] (Cp* = .eta.5-C5Me5; R = Pri, 2,6-Me2C6H3) and Isolation of.mu.-Phenyldiazene Complexes [Cp*Ru(.mu.-PhN:NH)(.mu.-SR)2RuCp*], Inorganic Chemistry, vol.33, issue.17, pp.3619-3620, 1994.
DOI : 10.1021/ic00095a001

Y. Li, Y. Li, B. Wang, Y. Luo, D. Yang et al., Ammonia formation by a thiolate-bridged diiron amide complex as a nitrogenase mimic, Nature Chemistry, vol.5, issue.4, pp.320-326, 2013.
DOI : 10.1021/om00151a016

R. Castarlenas, A. Di-giuseppe, J. J. Pérez-torrente, and L. A. Oro, The Emergence of Transition-Metal-Mediated Hydrothiolation of Unsaturated Carbon-Carbon Bonds: A Mechanistic Outlook, Angewandte Chemie International Edition, vol.70, issue.1, pp.211-222, 2013.
DOI : 10.1039/j19680002516

L. Palacios, M. J. Artigas, V. Polo, F. J. Lahoz, R. Castarlenas et al., Hydroxo???Rhodium???N-Heterocyclic Carbene Complexes as Efficient Catalyst Precursors for Alkyne Hydrothiolation, ACS Catalysis, vol.3, issue.12, pp.2910-2919, 2013.
DOI : 10.1021/cs400739y

M. Herberhold, H. Yan, W. Milius, and B. Wrackmeyer, Metal-Induced B???H Activation: Addition of Methyl Acetylene Carboxylates to Cp*Rh-, Cp*Ir-, (p-cymene)Ru-, and (p-cymene)Os Half-Sandwich Complexes Containing the Chelating 1,2-Dicarba-closo-dodecaborane- 1,2-dithiolate Ligand, Chemistry - A European Journal, vol.6, issue.16, pp.3026-3032, 2000.
DOI : 10.1002/1521-3765(20000818)6:16<3026::AID-CHEM3026>3.0.CO;2-V

K. Kuniyasu, F. Yamashita, J. Terao, and N. Kambe, Definitive Evidence for the Insertion of Terminal Alkynes into ArylS???Pt Bonds: ???o-Halogen Effect??? in Stoichiometric and Catalytic Reactions, Angewandte Chemie International Edition, vol.22, issue.31, pp.5929-5933, 2007.
DOI : 10.1002/anie.200604986

U. Koelle, C. Rietman, J. Tjoe, T. Wagner, and U. Englebert, Alkyne Adducts of [Cp*Ru(SR)]2 and Intermediates of the Ruthenium Catalyzed Formation of Vinyl Thioethers (Z/E)-RSCR':CHR'' from RSH and R'C.tplbond.CR'', Organometallics, vol.14, issue.2, pp.703-713, 1995.
DOI : 10.1021/om00002a019

S. Lin, D. E. Herbet, A. Velian, M. W. Day, and T. Agapie, Dipalladium(I) Terphenyl Diphosphine Complexes as Models for Two-Site Adsorption and Activation of Organic Molecules, Journal of the American Chemical Society, vol.135, issue.42, pp.15830-15840, 2013.
DOI : 10.1021/ja406696k

. See, the recent review: V. Cadierno, J. Gimeno Chem. Rev, vol.109, pp.3512-3560, 2009.

). Capon, N. Le-berre-cosquer, B. L. Blanc, and R. Kergoat, Synthesis of secondary allenylidene-molybdenum complexes with a ferrocenyl substituent from carbenium ions species stabilized by two organometallic moieties, Journal of Organometallic Chemistry, vol.508, issue.1-2, pp.31-37, 1995.
DOI : 10.1016/0022-328X(95)05777-M

J. Espuelas, M. A. Esteruelas, F. J. Lahoz, L. A. Oro, and N. Ruiz, Synthesis of new hydride-carbyne and hydride-vinylcarbyne complexes of osmium(II) by reaction of OsH2Cl2(P-iso-Pr3)2 with terminal alkynes, Journal of the American Chemical Society, vol.115, issue.11, pp.4683-4689, 1993.
DOI : 10.1021/ja00064a032

J. Jaffart, M. Etienne, F. Maseras, J. E. Mcgrady, and O. Eisenstein, Equilibria between ??- and ??-Agostic Stabilized Rotamers of Secondary Alkyl Niobium Complexes, Journal of the American Chemical Society, vol.123, issue.25, pp.6000-6013, 2001.
DOI : 10.1021/ja0038169

J. R. Wigginton, S. J. Trepanier, R. Mcdonald, M. J. Ferguson, and M. Cowie, Bridging Methylene and Methyl Complexes of Rhodium/Osmium:?? Influence of the Ancillary Ligands on the Methyl Binding Mode, Organometallics, vol.24, issue.25, pp.6194-6211, 2005.
DOI : 10.1021/om0580405

P. Braunstein and N. M. Boag, Alkyl, Silyl, and Phosphane Ligands???Classical Ligands in Nonclassical Bonding Modes, Angewandte Chemie International Edition, vol.112, issue.180, pp.2427-2433, 2001.
DOI : 10.1021/ja00179a059
URL : http://onlinelibrary.wiley.com/doi/10.1002/1521-3773(20010817)40:16<2947::AID-ANIE55552947>3.0.CO;2-H/pdf

M. E. García, S. Melón, A. Ramos, V. Riera, M. A. Ruiz et al., A Versatile and Unprecedented Triply Bonded Dimolybdenum Carbonyl Anion, Organometallics, vol.22, issue.10, pp.1983-1985, 2003.
DOI : 10.1021/om030150t

M. A. Alvarez, D. García-vivó, M. E. García, M. E. Martinez, A. Ramos et al., ]: Migratory Behavior and Methylidyne Derivatives, Organometallics, vol.27, issue.9, pp.1973-1975, 2008.
DOI : 10.1021/om800061z

V. P. Boyarskiy, N. A. Bokach, K. V. Luzyanin, and V. Y. Kukushkin, Metal-Mediated and Metal-Catalyzed Reactions of Isocyanides, Chemical Reviews, vol.115, issue.7, pp.2698-2779, 2015.
DOI : 10.1021/cr500380d

). L. Busetto, F. Marchetti, S. Zacchini, V. Zanotti, and E. Zoli, Nitrile ligands activation in dinuclear aminocarbyne complexes, Journal of Organometallic Chemistry, vol.690, issue.8, pp.1959-1970, 2005.
DOI : 10.1016/j.jorganchem.2004.11.006

P. Schollhammer, F. Y. Pétillon, R. Pichon, S. Poder-guillou, J. Talarmin et al., Reactions of Di- and Polynuclear Complexes. 14. Synthesis of Permethylated-Cyclopentadienyl Chalcogeno-Bridged Compounds: A Route to the Stable Thiolatosulfidocarbonyldimolybdenum(III) Complex [Cp*2Mo2(CO)2(.mu.-SMe)2(.mu.-S)]. Crystal Structure Determination of [Cp*2Mo2(CO)2(.mu.-SMe)2(.mu.-SH)][BF4], Organometallics, vol.14, issue.5, pp.2277-2287, 1995.
DOI : 10.1021/om00005a029

). A. Baranger, T. A. Hanna, and R. G. Bergman, Transfer of Oxygen and Sulfur from Organic Molecules to a Zr-Ir Bond. Evidence for an Unusually Rapid Atom Abstraction Reaction, Journal of the American Chemical Society, vol.117, issue.40, pp.10041-10046, 1995.
DOI : 10.1021/ja00145a015

J. Gabay, S. Dietz, P. Bernatis, and M. R. Dubois, Dinuclear cyclopentadienylmolybdenum complexes containing thioether ligands. Ligand substitution and desulfurization reactions, Organometallic Modeling of the Hydrodesulfurization and Hydrodenitrogenation Reactions, Kluwer Academic, pp.3630-3635, 1993.
DOI : 10.1021/om00033a040